JEE MAIN · CHEMISTRY · STATES OF MATTER

JEE Main States of Matter Questions & Solutions

142 solved questions on States of Matter, ranging from easy to JEE-Advanced-flavour hard. Click any to see the full solution.

67Easy
73Medium
2Hard

All 142 questions

  1. Medium INTEGER +4 / -1 PYQ 2024

    $2.5 \mathrm{~g}$ of a non-volatile, non-electrolyte is dissolved in $100 \mathrm{~g}$ of water at $25^{\circ} \mathrm{C}$. The solution showed a boiling point elevation by…

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  2. Easy INTEGER +4 / -1 PYQ 2021

    At 363 K, the vapour pressure of A is 21 kPa and that of B is 18 kPa. One mole of A and 2 moles of B are mixed. Assuming that this solution is ideal, the vapour pressure of the…

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  3. Easy INTEGER +4 / -1 PYQ 2021

    The vapour pressures of A and B at 25$^\circ$C are 90 mm Hg and 15 mm Hg respectively. If A and B are mixed such that the mole fraction of A in the mixture is 0.6, then the mole…

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  4. Easy INTEGER +4 / -1 PYQ 2022

    $150 \mathrm{~g}$ of acetic acid was contaminated with $10.2 \mathrm{~g}$ ascorbic acid $\left(\mathrm{C}_{6} \mathrm{H}_{8} \mathrm{O}_{6}\right)$ to lower down its freezing…

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  5. Medium INTEGER +4 / -1 PYQ 2025

    When 1 g each of compounds AB and $\mathrm{AB}_2$ are dissolved in 15 g of water separately, they increased the boiling point of water by 2.7 K and 1.5 K respectively. The atomic…

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  6. Easy INTEGER +4 / -1 PYQ 2022

    The vapour pressures of two volatile liquids A and B at 25$^\circ$C are 50 Torr and 100 Torr, respectively. If the liquid mixture contains 0.3 mole fraction of A, then the mole…

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  7. Medium INTEGER +4 / -1 PYQ 2021

    224 mL of SO2(g) at 298 K and 1 atm is passed through 100 mL of 0.1 M NaOH solution. The non-volatile solute produced is dissolved in 36g of water. The lowering of vapour pressure…

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  8. Easy INTEGER +4 / -1 PYQ 2020

    How much amount of NaCl should be added to 600 g of water ($\rho$ = 1.00 g/mL) to decrease the freezing point of water to – 0.2 °C ? ______. (The freezing point depression…

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  9. Easy INTEGER +4 / -1 PYQ 2023

    Iron oxide FeO, crystallises in a cubic lattice with a unit cell edge length of 5.0 Å. If density of the $\mathrm{FeO}$ in the crystal is $4.0 \mathrm{~g} \mathrm{~cm}^{-3}$,…

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  10. Easy INTEGER +4 / -1 PYQ 2024

    An artificial cell is made by encapsulating $0.2 \mathrm{~M}$ glucose solution within a semipermeable membrane. The osmotic pressure developed when the artificial cell is placed…

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  11. Medium MCQ +4 / -1 PYQ 2022

    The depression in freezing point observed for a formic acid solution of concentration $0.5 \mathrm{~mL} \mathrm{~L}^{-1}$ is $0.0405^{\circ} \mathrm{C}$. Density of formic acid is…

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  12. Medium INTEGER +4 / -1 PYQ 2022

    Ionic radii of cation $\mathrm{A}^{+}$ and anion $\mathrm{B}^{-}$ are 102 and $181 \,\mathrm{pm}$ respectively. These ions are allowed to crystallize into an ionic solid. This…

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  13. Medium INTEGER +4 / -1 PYQ 2021

    At 20$^\circ$ C, the vapour pressure of benzene is 70 torr and that of methyl benzene is 20 torr. The mole fraction of benzene in the vapour phase at 20$^\circ$ above an equimolar…

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  14. Medium INTEGER +4 / -1 PYQ 2022

    1.2 mL of acetic acid is dissolved in water to make 2.0 L of solution. The depression in freezing point observed for this strength of acid is 0.0198$^\circ$C. The percentage of…

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  15. Medium MCQ +4 / -1 PYQ 2020

    At 35oC, the vapour pressure of CS2 is 512 mm. Hg and that of acetone is 344 mm Hg. A solution of CS2 in acetone has a total vapour pressure of 600 mm Hg. The false statement…

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  16. Easy INTEGER +4 / -1 PYQ 2023

    At $27^{\circ} \mathrm{C}$, a solution containing $2.5 \mathrm{~g}$ of solute in $250.0 \mathrm{~mL}$ of solution exerts an osmotic pressure of $400 \mathrm{~Pa}$. The molar mass…

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  17. Medium INTEGER +4 / -1 PYQ 2023

    80 mole percent of $\mathrm{MgCl}_{2}$ is dissociated in aqueous solution. The vapour pressure of $1.0 ~\mathrm{molal}$ aqueous solution of $\mathrm{MgCl}_{2}$ at $38^{\circ}…

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  18. Easy MCQ +4 / -1 PYQ 2023

    What weight of glucose must be dissolved in $100 \mathrm{~g}$ of water to lower the vapour pressure by $0.20 \mathrm{~mm} ~\mathrm{Hg}$ ? (Assume dilute solution is being formed)…

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  19. Easy INTEGER +4 / -1 PYQ 2021

    The unit cell of copper corresponds to a face centered cube of edge length 3.596 $\mathop A\limits^o$ with one copper atom at each lattice point. The calculated density of copper…

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  20. Medium INTEGER +4 / -1 PYQ 2023

    Lead storage battery contains $38 \%$ by weight solution of $\mathrm{H}_{2} \mathrm{SO}_{4}$. The van't Hoff factor is $2.67$ at this concentration. The temperature in Kelvin at…

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  21. Easy INTEGER +4 / -1 PYQ 2024

    The vapor pressure of pure benzene and methyl benzene at $27^{\circ} \mathrm{C}$ is given as 80 Torr and 24 Torr, respectively. The mole fraction of methyl benzene in vapor phase,…

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  22. Medium INTEGER +4 / -1 PYQ 2021

    Ga (atomic mass 70 u) crystallizes in a hexagonal close packed structure. The total number of voids in 0.581 g of Ga is __________ $\times$ 1021. (Round off to the Nearest…

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  23. Medium INTEGER +4 / -1 PYQ 2023

    Sea water contains $29.25 \% ~\mathrm{NaCl}$ and $19 \% ~\mathrm{MgCl}_{2}$ by weight of solution. The normal boiling point of the sea water is _____________ ${ }^{\circ}…

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  24. Easy MCQ +4 / -1 PYQ 2022

    Given below are two statements : one is labelled as Assertion (A) and the other is labelled as Reason (R). Assertion (A) : At 10$^\circ$C, the density of a 5 M solution of KCl…

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  25. Medium INTEGER +4 / -1 PYQ 2023

    Solution of $12 \mathrm{~g}$ of non-electrolyte (A) prepared by dissolving it in $1000 \mathrm{~mL}$ of water exerts the same osmotic pressure as that of $0.05 ~\mathrm{M}$…

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  26. Medium INTEGER +4 / -1 PYQ 2024

    Mass of ethylene glycol (antifreeze) to be added to $18.6 \mathrm{~kg}$ of water to protect the freezing point at $-24^{\circ} \mathrm{C}$ is ________ $\mathrm{kg}$ (Molar mass in…

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  27. Medium MCQ +4 / -1 PYQ 2020

    A diatomic molecule X2 has a body-centred cubic (bcc) structure with a cell edge of 300 pm. The density of the molecule is 6.17 g cm–3. The number of molecules present in 200 g…

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  28. Easy INTEGER +4 / -1 PYQ 2024

    The osmotic pressure of a dilute solution is $7 \times 10^5 \mathrm{~Pa}$ at $273 \mathrm{~K}$. Osmotic pressure of the same solution at $283 \mathrm{~K}$ is _________ $\times…

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  29. Medium MCQ +4 / -1 PYQ 2022

    Solute A associates in water. When 0.7 g of solute A is dissolved in 42.0 g of water, it depresses the freezing point by 0.2$^\circ$C. The percentage association of solute A in…

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  30. Medium INTEGER +4 / -1 PYQ 2022

    When a certain amount of solid A is dissolved in $100 \mathrm{~g}$ of water at $25^{\circ} \mathrm{C}$ to make a dilute solution, the vapour pressure of the solution is reduced to…

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  31. Medium INTEGER +4 / -1 PYQ 2021

    A solute A dimerizes in water. The boiling point of a 2 molal solution of A is 100.52$^\circ$C. The percentage association of A is __________. (Round off to the Nearest…

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  32. Medium INTEGER +4 / -1 PYQ 2022

    The distance between Na+ and Cl$-$ ions in solid NaCl of density 43.1 g cm$-$3 is _______________ $\times$ 10$-$10 m. (Nearest Integer) (Given : NA = 6.02 $\times$ 1023 mol$-$1)

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  33. Medium MCQ +4 / -1 PYQ 2023

    A compound is formed by two elements $\mathrm{X}$ and $\mathrm{Y}$. The element $\mathrm{Y}$ forms cubic close packed arrangement and those of element $\mathrm{X}$ occupy one…

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  34. Easy MCQ +4 / -1 PYQ 2023

    The correct relationships between unit cell edge length '$a$' and radius of sphere '$r$' for face-centred and body-centred cubic structures respectively are :

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  35. Hard MCQ +4 / -1 PYQ 2024

    The solution from the following with highest depression in freezing point/lowest freezing point is

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  36. Medium INTEGER +4 / -1 PYQ 2022

    Atoms of element X form hcp lattice and those of element Y occupy ${2 \over 3}$ of its tetrahedral voids. The percentage of element X in the lattice is ____________. (Nearest…

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  37. Easy INTEGER +4 / -1 PYQ 2022

    The osmotic pressure of blood is 7.47 bar at 300 K. To inject glucose to a patient intravenously, it has to be isotonic with blood. The concentration of glucose solution in gL$-$1…

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  38. Easy INTEGER +4 / -1 PYQ 2021

    40 g of glucose (Molar mass = 180) is mixed with 200 mL of water. The freezing point of solution is __________ K. (Nearest integer) [Given : Kf = 1.86 K kg mol$-$1; Density of…

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  39. Medium INTEGER +4 / -1 PYQ 2020

    If 250 cm3 of an aqueous solution containing 0.73 g of a protein A is isotonic with one litre of another aqueous solution containing 1.65 g of a protein B, at 298 K, the ratio of…

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  40. Easy INTEGER +4 / -1 PYQ 2022

    A solution containing 2.5 $\times$ 10$-$3 kg of a solute dissolved in 75 $\times$ 10$-$3 kg of water boils at 373.535 K. The molar mass of the solute is ____________ g mol$-$1.…

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  41. Medium INTEGER +4 / -1 PYQ 2020

    The elevation of boiling point of 0.10 m aqueous CrCl3.xNH3 solution is two times that of 0.05 m aqueous CaCl2 solution. The value of x is ______. [Assume 100% ionisation of the…

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  42. Easy INTEGER +4 / -1 PYQ 2022

    The elevation in boiling point for 1 molal solution of non-volatile solute A is $3 \mathrm{~K}$. The depression in freezing point for 2 molal solution of $\mathrm{A}$ in the same…

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  43. Easy INTEGER +4 / -1 PYQ 2023

    Sodium metal crystallizes in a body centred cubic lattice with unit cell edge length of $4~\mathop A\limits^o$. The radius of sodium atom is __________ $\times ~10^{-1}$ $\mathop…

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  44. Medium INTEGER +4 / -1 PYQ 2023

    $20 \%$ of acetic acid is dissociated when its $5 \mathrm{~g}$ is added to $500 \mathrm{~mL}$ of water. The depression in freezing point of such water is _________ $\times…

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  45. Medium INTEGER +4 / -1 PYQ 2024

    Considering acetic acid dissociates in water, its dissociation constant is $6.25 \times 10^{-5}$. If $5 \mathrm{~mL}$ of acetic acid is dissolved in 1 litre water, the solution…

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  46. Medium INTEGER +4 / -1 PYQ 2021

    The number of octahedral voids per lattice site in a lattice is _________. (Rounded off to the nearest integer)

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  47. Easy INTEGER +4 / -1 PYQ 2021

    AB2 is 10% dissociated in water to A2+ and B$-$. The boiling point of a 10.0 molal aqueous solution of AB2 is __________$^\circ$C. (Round off to the Nearest Integer).[Given :…

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  48. Easy MCQ +4 / -1 PYQ 2021

    Which one of the following 0.10 M aqueous solutions will exhibit the largest freezing point depression?

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  49. Easy INTEGER +4 / -1 PYQ 2022

    Metal $\mathrm{M}$ crystallizes into a fcc lattice with the edge length of $4.0 \times 10^{-8} \mathrm{~cm}$. The atomic mass of the metal is ____________ $\mathrm{g} /…

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  50. Medium INTEGER +4 / -1 PYQ 2021

    1.22 g of an organic acid is separately dissolved in 100 g of benzene (Kb = 2.6 K kg mol$-$1) and 100 g of acetone (Kb = 1.7 K kg mol$-$1). The acid is known to dimerize in…

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  51. Easy INTEGER +4 / -1 PYQ 2022

    If $\mathrm{O}_{2}$ gas is bubbled through water at $303 \mathrm{~K}$, the number of millimoles of $\mathrm{O}_{2}$ gas that dissolve in 1 litre of water is __________. (Nearest…

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  52. Easy MCQ +4 / -1 PYQ 2023

    Match List I with List II .tg {border-collapse:collapse;border-spacing:0;} .tg td{border-color:black;border-style:solid;border-width:1px;font-family:Arial,…

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  53. Medium INTEGER +4 / -1 PYQ 2024

    A solution containing $10 \mathrm{~g}$ of an electrolyte $\mathrm{AB}_2$ in $100 \mathrm{~g}$ of water boils at $100.52^{\circ} \mathrm{C}$. The degree of ionization of the…

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  54. Medium INTEGER +4 / -1 PYQ 2021

    The empirical formula for a compound with a cubic close packed arrangement of anions and with cations occupying all the octahedral sites in AxB. The value of x is _____________.…

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  55. Medium INTEGER +4 / -1 PYQ 2022

    In a solid AB, A atoms are in ccp arrangement and B atoms occupy all the octahedral sites. If two atoms from the opposite faces are removed, then the resultant stoichiometry of…

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  56. Easy INTEGER +4 / -1 PYQ 2021

    2 molal solution of a weak acid HA has a freezing point of 3.885$^\circ$C. The degree of dissociation of this acid is ___________ $\times$ 10$-$3. (Round off to the Nearest…

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  57. Easy INTEGER +4 / -1 PYQ 2021

    When 3.00 g of a substance 'X' is dissolved in 100 g of CCl4, it raises the boiling point by 0.60 K. The molar mass of the substance 'X' is ______________ g mol$-$1. (Nearest…

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  58. Medium INTEGER +4 / -1 PYQ 2022

    2.5 g of protein containing only glycine (C2H5NO2) is dissolved in water to make 500 mL of solution. The osmotic pressure of this solution at 300 K is found to be 5.03 $\times$…

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  59. Medium INTEGER +4 / -1 PYQ 2024

    $2.7 \mathrm{~kg}$ of each of water and acetic acid are mixed. The freezing point of the solution will be $-x^{\circ} \mathrm{C}$. Consider the acetic acid does not dimerise in…

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  60. Medium MCQ +4 / -1 PYQ 2021

    In a binary compound, atoms of element A form a hcp structure and those of element M occupy 2/3 of the tetrahedral voids of the hcp structure. The formula of the binary compound…

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  61. Easy MCQ +4 / -1 PYQ 2021

    The parameters of the unit cell of a substance are a = 2.5, b = 3.0, c = 4.0, $\alpha$ = 90$^\circ$, $\beta$ = 120$^\circ$, $\gamma$ = 90$^\circ$. The crystal system of the…

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  62. Medium MCQ +4 / -1 PYQ 2024

    Identify the mixture that shows positive deviations from Raoult's Law

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  63. Easy INTEGER +4 / -1 PYQ 2022

    The osmotic pressure exerted by a solution prepared by dissolving 2.0 g of protein of molar mass 60 kg mol$-$1 in 200 mL of water at 27$^\circ$C is ______________ Pa. [integer…

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  64. Medium INTEGER +4 / -1 PYQ 2023

    Consider the following pairs of solution which will be isotonic at the same temperature. The number of pairs of solutions is / are ___________. A. $1 ~\mathrm{M}$ aq.…

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  65. Hard INTEGER +4 / -1 PYQ 2023

    Solid Lead nitrate is dissolved in 1 litre of water. The solution was found to boil at 100.15$^\circ$C. When 0.2 mol of NaCl is added to the resulting solution, it was observed…

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  66. Medium INTEGER +4 / -1 PYQ 2021

    If a compound AB dissociates to the extent of 75% in an aqueous solution, the molality of the solution which shows a 2.5 K rise in the boiling point of the solution is…

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  67. Medium INTEGER +4 / -1 PYQ 2023

    Mass of Urea $\left(\mathrm{NH}_{2} \mathrm{CONH}_{2}\right)$ required to be dissolved in $1000 \mathrm{~g}$ of water in order to reduce the vapour pressure of water by $25 \%$ is…

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  68. Medium INTEGER +4 / -1 PYQ 2021

    1 kg of 0.75 molal aqueous solution of sucrose can be cooled up to $-$4$^\circ$C before freezing. The amount of ice (in g) that will be separated out is __________. (Nearest…

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  69. Medium INTEGER +4 / -1 PYQ 2021

    A certain element crystallises in a bcc lattice of unit cell edge length 27$\mathop A\limits^o$. If the same element under the same conditions crystallises in the fcc lattice, the…

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  70. Easy INTEGER +4 / -1 PYQ 2022

    2 g of a non-volatile non-electrolyte solute is dissolved in 200 g of two different solvents A and B whose ebullioscopic constants are in the ratio of 1 : 8. The elevation in…

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  71. Medium INTEGER +4 / -1 PYQ 2022

    An element M crystallises in a body centred cubic unit cell with a cell edge of $300 \,\mathrm{pm}$. The density of the element is $6.0 \mathrm{~g} \mathrm{~cm}^{-3}$. The number…

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  72. Medium INTEGER +4 / -1 PYQ 2020

    At 300 K, the vapour pressure of a solution containing 1 mole of n-hexane and 3 moles of n-heptane is 550 mm of Hg. At the same temperature, if one more mole of n-heptane is added…

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  73. Medium INTEGER +4 / -1 PYQ 2022

    A gaseous mixture of two substances A and B, under a total pressure of $0.8$ atm is in equilibrium with an ideal liquid solution. The mole fraction of substance A is $0.5$ in the…

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  74. Easy INTEGER +4 / -1 PYQ 2023

    An aqueous solution of volume $300 \mathrm{~cm}^{3}$ contains $0.63 \mathrm{~g}$ of protein. The osmotic pressure of the solution at $300 \mathrm{~K}$ is 1.29 mbar. The molar mass…

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  75. Medium MCQ +4 / -1 PYQ 2022

    An element X has a body centred cubic (bcc) structure with a cell edge of 200 pm. The density of the element is 5 g cm$-$3. The number of atoms present in 300 g of the element X…

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  76. Easy INTEGER +4 / -1 PYQ 2023

    25 mL of an aqueous solution of KCl was found to require 20 mL of 1 M $\mathrm{AgNO_3}$ solution when titrated using $\mathrm{K_2CrO_4}$ as an indicator. What is the depression in…

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  77. Easy INTEGER +4 / -1 PYQ 2023

    A metal M forms hexagonal close-packed structure. The total number of voids in 0.02 mol of it is _________ $\times$ $10^{21}$ (Nearest integer). (Given…

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  78. Easy MCQ +4 / -1 PYQ 2023

    A cubic solid is made up of two elements X and Y. Atoms of X are present on every alternate corner and one at the center of cube. Y is at $\frac{1}{3}^{\mathrm{rd}}$ of the total…

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  79. Easy INTEGER +4 / -1 PYQ 2023

    A metal M crystallizes into two lattices :- face centred cubic (fcc) and body centred cubic (bcc) with unit cell edge length of $2.0$ and $2.5\,\mathop A\limits^o$ respectively.…

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  80. Medium INTEGER +4 / -1 PYQ 2023

    0.004 M K$_2$SO$_4$ solution is isotonic with 0.01 M glucose solution. Percentage dissociation of K$_2$SO$_4$ is ___________ (Nearest integer)

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  81. Medium INTEGER +4 / -1 PYQ 2023

    The vapour pressure of $30 \%(\mathrm{w} / \mathrm{v})$ aqueous solution of glucose is __________ $\mathrm{mm} ~\mathrm{Hg}$ at $25^{\circ} \mathrm{C}$. [Given : The density of…

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  82. Easy MCQ +4 / -1 PYQ 2020

    A set of solutions is prepared using 180 g of water as a solvent and 10 g of different nonvolatile solutes A, B and C. The relative lowering of vapour pressure in the presence of…

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  83. Medium INTEGER +4 / -1 PYQ 2021

    KBr is doped with 10$-$5 mole percent of SrBr2. The number of cationic vacancies in 1g of KBr crystal is ____________ 1014. (Round off to the Nearest Integer).[Atomic Mass : K :…

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  84. Easy MCQ +4 / -1 PYQ 2022

    Boiling point of a $2 \%$ aqueous solution of a non-volatile solute A is equal to the boiling point of $8 \%$ aqueous solution of a non-volatile solute B. The relation between…

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  85. Easy INTEGER +4 / -1 PYQ 2020

    The osmotic pressure of a solution of NaCl is 0.10 atm and that of a glucose solution is 0.20 atm. The osmotic pressure of a solution formed by mixing 1 L of the sodium chloride…

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  86. Medium INTEGER +4 / -1 PYQ 2021

    1 molal aqueous solution of an electrolyte A2B3 is 60% ionised. The boiling point of the solution at 1 atm is _________ K. (Rounded off to the nearest integer)[Given Kb for (H2O)…

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  87. Easy MCQ +4 / -1 PYQ 2021

    Which one of the following 0.06 M aqueous solutions has lowest freezing point?

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  88. Easy INTEGER +4 / -1 PYQ 2022

    A company dissolves 'x' amount of CO2 at 298 K in 1 litre of water to prepare soda water. X = __________ $\times$ 10$-$3 g. (nearest integer) (Given : partial pressure of CO2 at…

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  89. Medium INTEGER +4 / -1 PYQ 2020

    An element with molar mass 2.7 $\times$ 10-2 kg mol-1 forms a cubic unit cell with edge length 405 pm. If its density is 2.7 $\times$ 103 kg m-3, the radius of the element is…

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  90. Medium MCQ +4 / -1 PYQ 2025

    1.24 g of AX2 (molar mass 124 g mol−1) is dissolved in 1 kg of water to form a solution with boiling point of 100.015°C, while 25.4 g of AY2 (molar mass 250 g mol−1) in 2 kg…

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  91. Medium INTEGER +4 / -1 PYQ 2022

    A 0.5 percent solution of potassium chloride was found to freeze at $-$0.24$^\circ$C. The percentage dissociation of potassium chloride is ______________. (Nearest integer) (Molal…

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  92. Medium INTEGER +4 / -1 PYQ 2023

    If the boiling points of two solvents X and Y (having same molecular weights) are in the ratio $2: 1$ and their enthalpy of vaporizations are in the ratio $1: 2$, then the boiling…

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  93. Easy INTEGER +4 / -1 PYQ 2021

    1.46 g of a biopolymer dissolved in a 100 mL water at 300 K exerted an osmotic pressure of 2.42 $\times$ 10$-$3 bar.The molar mass of the biopolymer is _____________ $\times$ 104…

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  94. Medium MCQ +4 / -1 PYQ 2020

    A crystal is made up of metal ions 'M1' and 'M2' and oxide ions. Oxide ions form a ccp lattice structure. The cation 'M1' occupies 50% of octahedral voids and the cation 'M2'…

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  95. Medium INTEGER +4 / -1 PYQ 2023

    The number of pairs of the solutions having the same value of the osmotic pressure from the following is _________. (Assume 100% ionization) A. 0.500 $\mathrm{M~C_2H_5OH~(aq)}$…

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  96. Medium MCQ +4 / -1 PYQ 2023

    Evaluate the following statements for their correctness. A. The elevation in boiling point temperature of water will be same for $0.1 \mathrm{M} \, \mathrm{NaCl}$ and $0.1…

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  97. Medium INTEGER +4 / -1 PYQ 2023

    An atomic substance A of molar mass $12 \mathrm{~g} \mathrm{~mol}^{-1}$ has a cubic crystal structure with edge length of $300 ~\mathrm{pm}$. The no. of atoms present in one unit…

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  98. Easy MCQ +4 / -1 PYQ 2024

    What happens to freezing point of benzene when small quantity of napthalene is added to benzene?

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  99. Medium INTEGER +4 / -1 PYQ 2021

    When 12.2 g of benzoic acid is dissolved in 100 g of water, the freezing point of solution was found to be $-$0.93$^\circ$C (Kf(H2O) = 1.86 K kg mol$-$1). The number (n) of…

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  100. Easy INTEGER +4 / -1 PYQ 2025

    If A2B is 30% ionised in an aqueous solution, then the value of van't Hoff factor (i) is _______ × 10−1.

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  101. Medium INTEGER +4 / -1 PYQ 2021

    A copper complex crystallising in a CCP lattice with a cell edge of 0.4518 nm has been revealed by employing X-ray diffraction studies. The density of a copper complex is found to…

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  102. Easy INTEGER +4 / -1 PYQ 2021

    83 g of ethylene glycol dissolved in 625 g of water. The freezing point of the solution is ____________ K. (Nearest integer)[Use : Molal Freezing point depression constant of…

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  103. Easy INTEGER +4 / -1 PYQ 2021

    The oxygen dissolved in water exerts a partial pressure of 20 kPa in the vapour above water. The molar solubility of oxygen in water is __________ $\times$ 10$-$5 mol dm$-$3.…

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  104. Easy INTEGER +4 / -1 PYQ 2022

    $1.80 \mathrm{~g}$ of solute A was dissolved in $62.5 \mathrm{~cm}^{3}$ of ethanol and freezing point of the solution was found to be $155.1 \mathrm{~K}$. The molar mass of solute…

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  105. Easy INTEGER +4 / -1 PYQ 2021

    CO2 gas is bubbled through water during a soft drink manufacturing process at 298 K. If CO2 exerts a partial pressure of 0.835 bar then x m mol of CO2 would dissolve in 0.9 L of…

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  106. Easy INTEGER +4 / -1 PYQ 2021

    C6H6 freezes at 5.5$^\circ$C. The temperature at which a solution of 10g of C4H10 in 200g of C6H6 freeze is __________ $^\circ$C. (The molal freezing point depression constant of…

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  107. Easy MCQ +4 / -1 PYQ 2022

    Two solutions A and B are prepared by dissolving 1 g of non-volatile solutes X and Y, respectively in 1 kg of water. The ratio of depression in freezing points for A and B is…

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  108. Easy INTEGER +4 / -1 PYQ 2023

    A solution containing $2 \mathrm{~g}$ of a non-volatile solute in $20 \mathrm{~g}$ of water boils at $373.52 \mathrm{~K}$. The molecular mass of the solute is ___________…

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  109. Easy INTEGER +4 / -1 PYQ 2021

    Of the following four aqueous solutions, total number of those solutions whose freezing point is lower than that of 0.10 M C2H5OH is __________ (Integer answer)(i) 0.10 M…

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  110. Easy INTEGER +4 / -1 PYQ 2022

    Elevation in boiling point for 1.5 molal solution of glucose in water is 4 K. The depression in freezing point for 4.5 molal solution of glucose in water is 4 K. The ratio of…

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  111. Easy INTEGER +4 / -1 PYQ 2023

    The total pressure observed by mixing two liquids A and B is 350 mm Hg when their mole fractions are 0.7 and 0.3 respectively. The total pressure becomes 410 mm Hg if the mole…

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  112. Medium INTEGER +4 / -1 PYQ 2023

    If the degree of dissociation of aqueous solution of weak monobasic acid is determined to be 0.3, then the observed freezing point will be ___________% higher than the…

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  113. Medium INTEGER +4 / -1 PYQ 2025

    Sea water, which can be considered as a 6 molar $(6 \mathrm{M})$ solution of NaCl , has a density of $2 \mathrm{~g} \mathrm{~mL}^{-1}$. The concentration of dissolved oxygen…

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  114. Easy MCQ +4 / -1 PYQ 2020

    Two open beakers one containing a solvent and the other containing a mixture of that solvent with a non voltatile solute are together selated in a container. Over time :

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  115. Easy MCQ +4 / -1 PYQ 2020

    The size of a raw mango shrinks to a much smaller size when kept in a concentrated salt solution. Which one of the following processes can explain this?

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  116. Easy MCQ +4 / -1 PYQ 2023

    In the depression of freezing point experiment A. Vapour pressure of the solution is less than that of pure solvent B. Vapour pressure of the solution is more than that of pure…

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  117. Easy MCQ +4 / -1 PYQ 2024

    A solution of two miscible liquids showing negative deviation from Raoult's law will have :

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  118. Medium MCQ +4 / -1 PYQ 2024

    We have three aqueous solutions of $\mathrm{NaCl}$ labelled as ' $\mathrm{A}$ ', ' $\mathrm{B}$ ' and ' $\mathrm{C}$ ' with concentration $0.1 \mathrm{M}$, $0.01 \mathrm{M}$ and…

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  119. Easy MCQ +4 / -1 PYQ 2025

    Arrange the following solutions in order of their increasing boiling points. (i) $10^{-4} \mathrm{M} \mathrm{NaCl}$ (ii) $10^{-4} \mathrm{M}$ Urea (iii) $10^{-3} \mathrm{M}…

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  120. Medium MCQ +4 / -1 PYQ 2025

    Consider a binary solution of two volatile liquid components 1 and $2 . x_1$ and $y_1$ are the mole fractions of component 1 in liquid and vapour phase, respectively. The slope…

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  121. Easy MCQ +4 / -1 PYQ 2025

    When a non-volatile solute is added to the solvent, the vapour pressure of the solvent decreases by 10 mm of Hg . The mole fraction of the solute in the solution is 0.2 . What…

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  122. Medium MCQ +4 / -1 PYQ 2025

    What is the freezing point depression constant of a solvent, 50 g of which contain 1 g non volatile solute (molar mass $256 \mathrm{~g} \mathrm{~mol}^{-1}$ ) and the decrease in…

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  123. Medium MCQ +4 / -1 PYQ 2025

    Assume a living cell with 0.9% (w/w) of glucose solution (aqueous). This cell is immersed in another solution having equal mole fraction of glucose and water. (Consider the data…

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  124. Easy MCQ +4 / -1 PYQ 2025

    Given below are two statements : Statement (I): NaCl is added to the ice at 0°C, present in the ice cream box to prevent the melting of ice cream. Statement (II): On addition of…

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  125. Medium MCQ +4 / -1 PYQ 2025

    A solution is made by mixing one mole of volatile liquid $A$ with 3 moles of volatile liquid $B$. The vapour pressure of pure A is 200 mm Hg and that of the solution is 500 mm Hg…

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  126. Easy MCQ +4 / -1 PYQ 2025

    2 moles each of ethylene glycol and glucose are dissolved in 500 g of water. The boiling point of the resulting solution is: (Given : Ebullioscopic constant of water $=0.52…

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  127. Medium MCQ +4 / -1 PYQ 2025

    Given below are two statements: Statement (I) : Molal depression constant $\mathrm{K}_f$ is given by $\frac{\mathrm{M}_1 \mathrm{RT}_f}{\Delta \mathrm{~S}_{\mathrm{fus}}}$, where…

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  128. Medium MCQ +4 / -1 PYQ 2025

    Match List - I with List - II. List - I List - II (A) Solution of chloroform and acetone (I) Minimum boiling azeotrope (B) Solution of ethanol and water (II) Dimerizes (C)…

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  129. Medium MCQ +4 / -1 PYQ 2025

    Liquid A and B form an ideal solution. The vapour pressures of pure liquids A and B are 350 and 750 mm Hg respectively at the same temperature. If $x_A$ and $x_B$ are the mole…

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  130. Medium MCQ +4 / -1 PYQ 2025

    Which of the following binary mixture does not show the behaviour of minimum boiling azeotropes?

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  131. Medium MCQ +4 / -1 PYQ 2025

    $\mathrm{HA}(a q) \rightleftharpoons \mathrm{H}^{+}(a q)+\mathrm{A}^{-}(a q)$The freezing point depression of a 0.1 m aqueous solution of a monobasic weak acid HA is 0.20 °C. The…

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  132. Easy INTEGER +4 / -1 PYQ 2021

    The coordination number of an atom in a body-centered cubic structure is _______. [Assume that the lattice is made up of atoms.]

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  133. Medium INTEGER +4 / -1 PYQ 2021

    Diamond has a three dimensional structure of C atoms formed by covalent bonds. The structure of diamond has face centred cubic lattice where 50% of the tetrahedral voids are also…

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  134. Medium INTEGER +4 / -1 PYQ 2022

    Metal deficiency defect is shown by Fe0.93O. In the crystal, some Fe2+ cations are missing and loss of positive charge is compensated by the presence of Fe3+ ions. The percentage…

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  135. Easy INTEGER +4 / -1 PYQ 2023

    Number of crystal systems from the following where body centred unit cell can be found, is ____________. Cubic, tetragonal, orthorhombic, hexagonal, rhombohedral, monoclinic,…

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  136. Medium MCQ +4 / -1 PYQ 2020

    Which of the following compounds is likely to show both Frenkel and Schottky defects in its crystalline form?

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  137. Easy MCQ +4 / -1 PYQ 2021

    A hard substance melts at high temperature and is an insulator in both solid and in molten state. This solid is most likely to be a/an :

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  138. Medium MCQ +4 / -1 PYQ 2021

    Given below are two statements. One is labelled as Assertion A nd the other is labelled as Reason R.Assertion A : Sharp glass edge becomes smooth on heating it upto its melting…

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  139. Easy MCQ +4 / -1 PYQ 2021

    Select the correct statements(A) Crystalline solids have long range order.(B) Crystalline solids are isotropic(C) Amorphous solid are sometimes called pseudo solids.(D) Amorphous…

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  140. Easy MCQ +4 / -1 PYQ 2021

    Given below are two statements.Statement I : Frenkel defects are vacancy as well as interstitial defects.Statement II : Frenkel defect leads to colour in ionic solids due to…

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  141. Easy MCQ +4 / -1 PYQ 2022

    The incorrect statement about the imperfections in solids is :

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  142. Easy MCQ +4 / -1 PYQ 2023

    Which of the following expressions is correct in case of a $\mathrm{CsCl}$ unit cell (edge length 'a')?

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