An element with molar mass 2.7 $\times$ 10-2 kg mol-1 forms a cubic unit cell with edge length 405 pm. If its density is 2.7 $\times$ 103 kg m-3, the radius of the element is approximately ______ $\times$ 10-12 m (to the nearest integer).
Answer (integer)
143
Solution
Molar mass of an element (M) = 27 gm mol<sup>–1</sup>
<br><br>Edge length of a cubic unit cell (a) = 405 pm = 4.05 × 10<sup>–8</sup> cm
<br><br>density of the element (d) = 2.7 gm/cc
<br><br>d = ${{Z \times M} \over {{N_A} \times {{\left( a \right)}^3}}}$
<br><br>$\Rightarrow$ 2.7 = $${{Z \times 27} \over {6 \times {{10}^{23}} \times {{\left( {4.05 \times {{10}^{ - 8}}} \right)}^3}}}$$
<br><br>$\Rightarrow$ Z = 4
<br><br>The element has fcc unit cell
<br><br>$\therefore$ $\sqrt 2$a = 4r
<br><br>$\Rightarrow$ r = ${{1.414 \times 405} \over 4}$
<br><br>= 143 pm
<br><br>= 143 × 10<sup>–12</sup> m
About this question
Subject: Chemistry · Chapter: States of Matter · Topic: Gas Laws
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