Medium INTEGER +4 / -1 PYQ · JEE Mains 2020

If 250 cm3 of an aqueous solution containing 0.73 g of a protein A is isotonic with one litre of another aqueous solution containing 1.65 g of a protein B, at 298 K, the ratio of the molecular masses of A and B is ______ × 10–2 (to the nearest integer).

Answer (integer) 177

Solution

Let molar mass of protein A = x g/mol <br><br>Let molar mass of protein B = y g/mol <br><br>$\pi$<sub>A</sub> = osmotic pressure of protein A = ${{0.73} \over x} \times {{1000} \over {250}} \times RT$ <br><br>$\pi$<sub>B</sub> = osmotic pressure of protein B = ${{1.65} \over y} \times {1 \over 1} \times RT$ <br><br>Given $\pi$<sub>A</sub> = $\pi$<sub>B</sub> <br><br>$\Rightarrow$ ${{0.73} \over x} \times {{1000} \over {250}} \times RT$ = ${{1.65} \over y} \times {1 \over 1} \times RT$ <br><br>$\Rightarrow$ ${x \over y}$ = ${{0.73} \over {0.25 \times 1.65}}$ = 1.77 <br><br>= 177 $\times$ 10<sup>-2</sup>

About this question

Subject: Chemistry · Chapter: States of Matter · Topic: Gas Laws

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