Medium INTEGER +4 / -1 PYQ · JEE Mains 2022

A 0.5 percent solution of potassium chloride was found to freeze at $-$0.24$^\circ$C. The percentage dissociation of potassium chloride is ______________. (Nearest integer)

(Molal depression constant for water is 1.80 K kg mol$-$1 and molar mass of KCl is 74.6 g mol$-$1)

Answer (integer) 98

Solution

$\Delta \mathrm{T}_{\mathrm{f}}=\mathrm{iK}_{\mathrm{b}} \mathrm{m}$ <br/><br/> $$ \begin{aligned} &\mathrm{i}=\frac{0.24 \times 99.5 \times 74.6}{1.80 \times 0.5 \times 1000} \\\\ &=1.98 \\\\ &\alpha=\frac{\mathrm{i}-1}{\mathrm{n}-1}=\frac{0.98}{1}=0.98 = 98 \,\% \end{aligned} $$

About this question

Subject: Chemistry · Chapter: States of Matter · Topic: Gas Laws

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