Medium MCQ +4 / -1 PYQ · JEE Mains 2024

During an adiabatic process, if the pressure of a gas is found to be proportional to the cube of its absolute temperature, then the ratio of $\frac{\mathrm{C}_{\mathrm{P}}}{\mathrm{C}_{\mathrm{V}}}$ for the gas is :

  1. A $\frac{5}{3}$
  2. B $\frac{3}{2}$ Correct answer
  3. C $\frac{7}{5}$
  4. D $\frac{9}{7}$

Solution

<p>To begin with, we're told that during an adiabatic process, the pressure $P$ of a gas is directly proportional to the cube of its absolute temperature $T$, that is, $P \propto T^3$. From this, we can express the relation as $P = kT^3$, where $k$ is a constant.</p> <p>In an adiabatic process, $PV^\gamma = \text{constant}$, where $\gamma = \frac{C_P}{C_V}$, $P$ is the pressure, $V$ is the volume, $C_P$ is the heat capacity at constant pressure, and $C_V$ is the heat capacity at constant volume.</p> <p>Also, the ideal gas equation is $PV = nRT$, where $n$ is the amount of substance, $R$ is the ideal gas constant, and $T$ is the absolute temperature. This can be rearranged to express $P$ in terms of $T$ and $V$, resulting in $P = \frac{nRT}{V}$.</p> <p>Given that $P = kT^3$, we can equate this to the expression we got from the ideal gas law: $\frac{nRT}{V} = kT^3$. Simplifying, we get $V = \frac{nR}{kT^2}$, which shows that $V$ is inversely proportional to $T^2$.</p> <p>Now, let's recall the adiabatic condition $PV^\gamma = \text{constant}$. Substituting the proportionalities $P \propto T^3$ and $V \propto T^{-2}$ into this equation, it becomes $T^3(T^{-2})^\gamma = \text{constant}$, simplifying to $T^{3-2\gamma} = \text{constant}$.</p> <p>For the expression $T^{3-2\gamma} = \text{constant}$ to hold true in an adiabatic process, where the only variable is temperature $T$, the exponent must equal to zero (as the quantity of $T$ to some power equals to a constant suggests that the change in $T$ does not alter the value of the expression). This implies $3 - 2\gamma = 0$, solving for $\gamma$: <p>$3 - 2\gamma = 0 \implies 2\gamma = 3 \implies \gamma = \frac{3}{2}$</p> <p>Therefore, the ratio of $\frac{C_P}{C_V}$ for the gas is $\frac{3}{2}$, which matches with Option B $\frac{3}{2}$.</p>

About this question

Subject: Physics · Chapter: Thermodynamics · Topic: Thermodynamic Processes

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