100 mL of 0.3 M acetic acid is shaken with 0.8 g of wood charcoal. The final concentration of acetic acid in the solution after adsorption is 0.125 M. The mass of acetic acid adsorbed per gram of carbon is _____________ $\times$ 10$-$4 g.
(Given : Molar mass of acetic acid = 60 g mol$-$1)
Answer (integer)
13125
Solution
$$
\begin{aligned}
&\text { Initial moles of acetic acid }=M_{1} \times V_{1} \\\\
&=100 \times 0.3=30 \mathrm{~m} \mathrm{~mol} .
\end{aligned}
$$
<br/><br/>
$$
\begin{aligned}
&\text { moles after adsorption }=100 \times 0.125=12.5 \mathrm{~m} \mathrm{~mol} \text {. } \\\\
&\text { moles adsorbed }=30-12.5=17.5 \mathrm{~m} \mathrm{~mol}
\end{aligned}
$$
<br/><br/>
for acetic acid; weight adsorbed.<br/><br/>
$$
\begin{aligned}
&\text { moles }=\frac{\text { Weight }}{\text { Molar Mass }} \\\\
&\text { weight }=17.5 \times 10^{-3} \times 60=1050 \times 10^{-3} \mathrm{~g} \\\\
&\text { for } 0.8 \mathrm{~g} \text { charcoal mass of acetic acid adsorbed } \\\\
&=1050 \times 10^{-3} \mathrm{~g} \\\\
&1 \mathrm{~g} \text { charcoal }=\frac{1050 \times 10^{-3}}{0.8}=1312.5 \times 10^{-3} \mathrm{~g} \\\\
&=13125 \times 10^{-4} \mathrm{~g}
\end{aligned}
$$
About this question
Subject: Chemistry · Chapter: Surface Chemistry · Topic: Adsorption
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