Easy MCQ +4 / -1 PYQ · JEE Mains 2022

TLC analysis of a mixture having 3 components (A, B, C) using silica gel as the stationary phase gave following Rf values; for A = 0.72, B = 0.48, C = 0.20.

Regarding the above observations, which one of the following statements is not correct for column chromatography of the mixture?

  1. A A is the most non-polar component
  2. B C is the most soluble component in mobile phase Correct answer
  3. C A will be eluted first
  4. D C is the most strongly absorbed component

Solution

The $\mathrm{R}_{f}$ (retardation factor) value is the ratio of the Solute's distance travelled to the Solvent's distance travelled. <br/><br/> Polar molecules will attract more toward adsorbent and cover smaller distance from the baseline. A has maximum $\mathrm{R}_{f}$ so it will less adsorbed on the adsorbent surface and travel faster and will be eluded first. <br/><br/> $\mathrm{C}$ has minimum $\mathrm{R}_{f}$ value. So it is more strongly adsobred and less soluble in mobile phase.

About this question

Subject: Chemistry · Chapter: Surface Chemistry · Topic: Adsorption

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