The oxidation states of nitrogen in NO, NO2, N2O and NO$_3^ -$ are in the order of :
Solution
<p>To determine the oxidation states of nitrogen in each compound, we consider the overall charge of the compound and the known oxidation states of other elements involved, typically oxygen.</p>
<p><strong>NO (Nitric Oxide)</strong>:</p>
<p><p>Oxygen generally has an oxidation state of $-2$.</p></p>
<p><p>Let the oxidation state of nitrogen in NO be $x$.</p></p>
<p><p>The equation: $x + (-2) = 0$.</p></p>
<p><p>Solving for $x$, we find $x = +2$.</p></p>
<p><strong>NO$_2$ (Nitrogen Dioxide)</strong>:</p>
<p><p>Oxygen has an oxidation state of $-2$.</p></p>
<p><p>Let the oxidation state of nitrogen be $x$.</p></p>
<p><p>The equation: $x + 2(-2) = 0$.</p></p>
<p><p>Solving for $x$, we find $x = +4$.</p></p>
<p><strong>N$_2$O (Dinitrogen Monoxide or Nitrous Oxide)</strong>:</p>
<p><p>Oxygen has an oxidation state of $-2$.</p></p>
<p><p>Let each nitrogen atom have an oxidation state of $x$.</p></p>
<p><p>The equation: $2x + (-2) = 0$.</p></p>
<p><p>Solving for $x$, we find $x = +1$.</p></p>
<p><strong>NO$_3^-$ (Nitrate Ion)</strong>:</p>
<p><p>Oxygen has an oxidation state of $-2$.</p></p>
<p><p>The overall charge of the ion is $-1$.</p></p>
<p><p>Let the oxidation state of nitrogen be $x$.</p></p>
<p><p>The equation: $x + 3(-2) = -1$.</p></p>
<p><p>Solving for $x$, we find $x = +5$.</p></p>
<p>Therefore, the oxidation states of nitrogen are:</p>
<p><p>NO: $+2$</p></p>
<p><p>NO$_2$: $+4$</p></p>
<p><p>N$_2$O: $+1$</p></p>
<p><p>NO$_3^-$: $+5$</p></p>
<p>The order of oxidation states from highest to lowest is:</p>
<p>NO$_3^-$ ($+5$) > NO$_2$ ($+4$) > NO ($+2$) > N$_2$O ($+1$)</p>
<p>Thus, the correct option is:</p>
<p>Option D</p>
<p>NO$_3^-$ > NO$_2$ > NO > N$_2$O</p>
About this question
Subject: Chemistry · Chapter: Redox Reactions · Topic: Oxidation States
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