Medium MCQ +4 / -1 PYQ · JEE Mains 2024

The number of ions from the following that are expected to behave as oxidising agent is :

$$\mathrm{Sn}^{4+}, \mathrm{Sn}^{2+}, \mathrm{Pb}^{2+}, \mathrm{Tl}^{3+}, \mathrm{Pb}^{4+}, \mathrm{Tl}^{+}$$

  1. A 3
  2. B 4
  3. C 2 Correct answer
  4. D 1

Solution

<p>Due to inert pair effect $\mathrm{Pb}^{2+}$ is more stable than $\mathrm{Pb}^{4+}$ and $\mathrm{Tl}^{+}$ is more stable than $\mathrm{Tl}^{3+}$. Therefore, $\mathrm{Pb}^{4+}$ and $\mathrm{T}^{3+}$ will function as oxidising agents and easily get reduced to $\mathrm{Pb}^{2+}$ and $\mathrm{TI}^{+}$ respectively.</p>

About this question

Subject: Chemistry · Chapter: Redox Reactions · Topic: Oxidation States

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