Medium MCQ +4 / -1 PYQ · JEE Mains 2021

The absolute value of the electron gain enthalpy of halogens satisfies :

  1. A Cl > Br > F > I
  2. B Cl > F > Br > I Correct answer
  3. C I > Br > Cl > F
  4. D F > Cl > Br > I

Solution

The magnitude of electron gain enthalpy of halogen atoms down the group show abnormal behavior. The |ΔH<sub>eg</sub>| of F is lower than that of Cl due to its smaller size. The incoming electron experiences higher repulsive force due to valence electrons of F than Cl. The correct order is Cl &gt; F &gt; Br &gt; I.

About this question

Subject: Chemistry · Chapter: Periodic Table and Periodicity · Topic: Periodic Trends

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