Easy MCQ +4 / -1 PYQ · JEE Mains 2024

Match List I with List II

LIST I
(Element)
LIST II
(Electronic Configuration)
A. $\mathrm{N}$ I. $[\mathrm{Ar}] 3 \mathrm{~d}^{10} 4 \mathrm{~s}^2 4 \mathrm{p}^5$
B. $\mathrm{S}$ II. $[\mathrm{Ne}] 3 \mathrm{~s}^2 3 \mathrm{p}^4$
C. $\mathrm{Br}$ III. $[\mathrm{He}] 2 \mathrm{~s}^2 2 \mathrm{p}^3$
D. $\mathrm{Kr}$ IV. $[\mathrm{Ar}] 3 \mathrm{~d}^{10} 4 \mathrm{~s}^2 4 \mathrm{p}^6$

Choose the correct answer from the options given below:

  1. A A-IV, B-III, C-II, D-I
  2. B A-I, B-IV, C-III, D-II
  3. C A-III, B-II, C-I, D-IV Correct answer
  4. D A-II, B-I, C-IV, D-III

Solution

<p>To match each element with its correct electronic configuration, let's consider the electronic configurations of each element based on their positions in the periodic table:</p> <ul> <li><b>Nitrogen (N)</b>: It is in the 2nd period and belongs to the p-block, specifically group 15. The electronic configuration of nitrogen is $1\text{s}^2 2\text{s}^2 2\text{p}^3$. Looking at the options in List II, this matches with the electronic configuration labeled 'III' ($[\mathrm{He}] 2 \mathrm{s}^2 2 \mathrm{p}^3$), which reflects the electronic configuration of nitrogen starting after the helium core.</li> <br/><li><b>Sulfur (S)</b>: Sulfur is in the 3rd period, also in the p-block, specifically group 16. Its electronic configuration is $1\text{s}^2 2\text{s}^2 2\text{p}^6 3\text{s}^2 3\text{p}^4$. In the given list, this corresponds to 'II' ($[\mathrm{Ne}] 3 \mathrm{s}^2 3 \mathrm{p}^4$), which captures the configuration of sulfur starting after the neon core.</li> <br/><li><b>Bromine (Br)</b>: Bromine is located in the 4th period and in the p-block, belonging to group 17. Its electronic configuration is $$1\text{s}^2 2\text{s}^2 2\text{p}^6 3\text{s}^2 3\text{p}^6 3\text{d}^{10} 4\text{s}^2 4\text{p}^5$$, which is correctly represented by 'I' ($[\mathrm{Ar}] 3 \mathrm{d}^{10} 4 \mathrm{s}^2 4 \mathrm{p}^5$), showing the configuration after the argon core.</li> <br/><li><b>Krypton (Kr)</b>: Krypton falls in the 4th period and is a noble gas situated in the p-block at group 18. Its electronic configuration is $$1\text{s}^2 2\text{s}^2 2\text{p}^6 3\text{s}^2 3\text{p}^6 3\text{d}^{10} 4\text{s}^2 4\text{p}^6$$, which aligns with 'IV' ($[\mathrm{Ar}] 3 \mathrm{d}^{10} 4 \mathrm{s}^2 4 \mathrm{p}^6$), clearly depicting krypton's electronic configuration post-argon.</li> </ul> <p>Therefore, the correct match is:</p> <ol> <li>A-III (Nitrogen matches with $[\mathrm{He}] 2 \mathrm{s}^2 2 \mathrm{p}^3$)</li> <li>B-II (Sulfur matches with $[\mathrm{Ne}] 3 \mathrm{s}^2 3 \mathrm{p}^4$)</li> <li>C-I (Bromine matches with $[\mathrm{Ar}] 3 \mathrm{d}^{10} 4 \mathrm{s}^2 4 \mathrm{p}^5$)</li> <li>D-IV (Krypton matches with $[\mathrm{Ar}] 3 \mathrm{d}^{10} 4 \mathrm{s}^2 4 \mathrm{p}^6$)</li> </ol> <p>Thus, the correct answer is <b>Option C</b>: A-III, B-II, C-I, D-IV.</p>

About this question

Subject: Chemistry · Chapter: Periodic Table and Periodicity · Topic: Periodic Trends

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