Medium MCQ +4 / -1 PYQ · JEE Mains 2023

For lead storage battery pick the correct statements

A. During charging of battery, $\mathrm{PbSO}_{4}$ on anode is converted into $\mathrm{PbO}_{2}$

B. During charging of battery, $\mathrm{PbSO}_{4}$ on cathode is converted into $\mathrm{PbO}_{2}$

C. Lead storage battery consists of grid of lead packed with $\mathrm{PbO}_{2}$ as anode

D. Lead storage battery has $\sim 38 \%$ solution of sulphuric acid as an electrolyte

Choose the correct answer from the options given below:

  1. A A, B, D only
  2. B B, C only
  3. C B, C, D only
  4. D B, D only Correct answer

Solution

<p>Let&#39;s review each statement:</p> <p>A. During charging of battery, PbSO₄ on anode is converted into PbO₂.</p> <ul> <li>This statement is incorrect. During charging, PbSO₄ on the anode (lead plate) is converted to Pb, not PbO₂.</li> </ul> <p>B. During charging of battery, PbSO₄ on cathode is converted into PbO₂.</p> <ul> <li>This statement is correct. During charging, PbSO₄ on the cathode (lead dioxide plate) is converted back to PbO₂.</li> </ul> <p>C. Lead storage battery consists of grid of lead packed with PbO₂ as anode.</p> <ul> <li>This statement is incorrect. The anode in a lead-acid battery is made of lead (Pb), not lead dioxide (PbO₂). The cathode is made of lead dioxide (PbO₂).</li> </ul> <p>D. Lead storage battery has ∼38% solution of sulphuric acid as an electrolyte.</p> <ul> <li>This statement is correct. The electrolyte in a lead-acid battery is a solution of about 35-38% sulfuric acid (H₂SO₄) in water.</li> </ul> <p>Therefore, the correct answer is:</p> <p>B, D only.</p>

About this question

Subject: Chemistry · Chapter: Electrochemistry · Topic: Electrochemical Cells

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