Medium INTEGER +4 / -1 PYQ · JEE Mains 2020

What would be the electrode potential for the given half cell reaction at pH = 5? ______.

2H2O $\to$ O2 + 4H$\oplus$ + 4e ; $E_{red}^0$ = 1.23 V

(R = 8.314 J mol–1 K–1 ; Temp = 298 k;

oxygen under std. atm. pressure of 1 bar)

Answer (integer) 1

Solution

E = E<sub>0</sub> - ${{0.0591} \over 4}\log {\left[ {{H^ + }} \right]^4}$ <br><br>$\Rightarrow$ E = 1.23 + 0.0591 × pH <br><br>$\Rightarrow$ E = 1.23 + 0.0591 × (5) <br><br>$\Rightarrow$ E = 1.52

About this question

Subject: Chemistry · Chapter: Electrochemistry · Topic: Electrochemical Cells

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