Medium MCQ +4 / -1 PYQ · JEE Mains 2023

The standard electrode potential of $\mathrm{M}^{+} / \mathrm{M}$ in aqueous solution does not depend on

  1. A Ionisation of a gaseous metal atom
  2. B Sublimation of a solid metal
  3. C Ionisation of a solid metal atom Correct answer
  4. D Hydration of a gaseous metal ion

Solution

<p>The standard electrode potential (E°) of a metal ion M<sup>+</sup>/M in aqueous solution is calculated under standard conditions and relates to the tendency of the M<sup>+</sup> ion to gain an electron to form the neutral metal atom, M. </p> <p>This is indeed a redox (reduction-oxidation) process, and the standard electrode potential is defined for the reduction half-reaction. E° values are based on the energies involved in the processes of ionization and hydration. </p> <p>However, the standard electrode potential does not depend on the state (solid, liquid, gas) of the atom being ionized. Ionization of a solid metal atom (Option C) would not directly impact the electrode potential as it is not inherently part of the process of reduction at the electrode that the E° values are measuring.</p> <p>The correct answer should be Option C : Ionisation of a solid metal atom.</p>

About this question

Subject: Chemistry · Chapter: Electrochemistry · Topic: Electrochemical Cells

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