Medium MCQ +4 / -1 PYQ · JEE Mains 2024

Alkaline oxidative fusion of $\mathrm{MnO}_2$ gives "A" which on electrolytic oxidation in alkaline solution produces B. A and B respectively are

  1. A $\mathrm{Mn}_2 \mathrm{O}_3$ and $\mathrm{MnO}_4^{2-}$
  2. B $\mathrm{Mn}_2 \mathrm{O}_7$ and $\mathrm{MnO}_4^{-}$
  3. C $\mathrm{MnO}_4^{2-}$ and $\mathrm{MnO}_4^{-}$ Correct answer
  4. D $\mathrm{MnO}_4^{2-}$ and $\mathrm{Mn}_2 \mathrm{O}_7$

Solution

<p>Alkaline oxidative fusion of $\mathrm{MnO}_2$ :</p> <p>$$2 \mathrm{MnO}_2+4 \mathrm{OH}^{-}+\mathrm{O}_2 \rightarrow 2 \mathrm{MnO}_4^{2-}+2 \mathrm{H}_2 \mathrm{O}$$</p> <p>Electrolytic oxidation of $\mathrm{MnO}_4^{2-}$ in alkaline medium.</p> <p>$\mathrm{MnO}_4^{2-} \rightarrow \mathrm{MnO}_4^{-}+e^{-}$</p>

About this question

Subject: Chemistry · Chapter: Electrochemistry · Topic: Electrochemical Cells

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