Medium MCQ +4 / -1 PYQ · JEE Mains 2023

The standard electrode potential $\mathrm{(M^{3+}/M^{2+})}$ for V, Cr, Mn & Co are $-$0.26 V, $-$0.41 V, + 1.57 V and + 1.97 V, respectively. The metal ions which can liberate $\mathrm{H_2}$ from a dilute acid are :

  1. A $\mathrm{Mn^{2+}}$ and $\mathrm{Co^{2+}}$
  2. B $\mathrm{V^{2+}}$ and $\mathrm{Mn^{2+}}$
  3. C $\mathrm{V^{2+}}$ and $\mathrm{Cr^{2+}}$ Correct answer
  4. D $\mathrm{Cr^{2+}}$ and $\mathrm{Co^{2+}}$

Solution

Metal cation with $(-)$ value of reduction potential $\left(\mathrm{M}^{+3} / \mathrm{M}^{+2}\right)$ or with $(+)$ value of oxidation potential $\left(\mathrm{M}^{+2} / \mathrm{M}^{+3}\right)$ will liberate $\mathrm{H}_{2}$<br/><br/> Therefore they will reduce $\mathrm{H}^{+}$ i. $\mathrm{e~V}^{+2}$ and $\mathrm{Cr}^{+2}$

About this question

Subject: Chemistry · Chapter: Electrochemistry · Topic: Electrochemical Cells

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