Medium INTEGER +4 / -1 PYQ · JEE Mains 2022

${[Fe{(CN)_6}]^{4 - }}$

${[Fe{(CN)_6}]^{3 - }}$

${[Ti{(CN)_6}]^{3 - }}$

${[Ni{(CN)_4}]^{2 - }}$

${[Co{(CN)_6}]^{3 - }}$

Among the given complexes, number of paramagnetic complexes is ____________.

Answer (integer) 2

Solution

$\left[\mathrm{Fe}(\mathrm{CN})_6\right]^{4-} \quad$ Diamagnetic<br/><br/> $\left[\mathrm{Fe}(\mathrm{CN})_6\right]^{3-} \quad$ Paramagnetic (1 unpaired electron)<br/><br/> $\left[\mathrm{Ti}(\mathrm{CN})_6\right]^{3-} \quad$ Paramagnetic (1 unpaired electron)<br/><br/> $\left[\mathrm{Ni}(\mathrm{CN})_4\right]^{2-} \quad$ Diamagnetic<br/><br/> $\left[\mathrm{Co}(\mathrm{CN})_6\right]^{3-} \quad$ Diamagnetic

About this question

Subject: Chemistry · Chapter: Coordination Compounds · Topic: Ligands and Coordination Number

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