Medium MCQ +4 / -1 PYQ · JEE Mains 2024

Number of complexes from the following with even number of unpaired "$\mathrm{d}$" electrons is ________ $$[\mathrm{V}(\mathrm{H}_2 \mathrm{O})_6]^{3+},[\mathrm{Cr}(\mathrm{H}_2 \mathrm{O})_6]^{2+},[\mathrm{Fe}(\mathrm{H}_2 \mathrm{O})_6]^{3+},[\mathrm{Ni}(\mathrm{H}_2 \mathrm{O})_6]^{3+},[\mathrm{Cu}(\mathrm{H}_2 \mathrm{O})_6]^{2+}$$ [Given atomic numbers: $\mathrm{V}=23, \mathrm{Cr}=24, \mathrm{Fe}=26, \mathrm{Ni}=28 \mathrm{Cu}=29$]

  1. A 1
  2. B 5
  3. C 2 Correct answer
  4. D 4

Solution

<p>$\left[\mathrm{V}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right]^{3+} \rightarrow 2$ unpaired electrons</p> <p>$$\left[\mathrm{Cr}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right]^{2+} \rightarrow 4$$ unpaired electrons</p> <p>Above 2 complex have even number of unpaired electrons.</p>

About this question

Subject: Chemistry · Chapter: Coordination Compounds · Topic: Ligands and Coordination Number

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