$\mathrm{Fe}^{3+}$ cation gives a prussian blue precipitate on addition of potassium ferrocyanide solution due to the formation of :
Solution
$4 \mathrm{Fe}^{3+}+3\left[\mathrm{Fe}(\mathrm{CN})_6\right]^{-4} \longrightarrow\underset{\text{Prussian Blue}} {\mathrm{Fe}_4\left[\mathrm{Fe}(\mathrm{CN})_6\right]_3}$
About this question
Subject: Chemistry · Chapter: Coordination Compounds · Topic: Ligands and Coordination Number
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