At 25$^\circ$C and 1 atm pressure, the enthalpy of combustion of benzene (I) and acetylene (g) are $-$ 3268 kJ mol$-$1 and $-$1300 kJ mol$-$1, respectively. The change in enthalpy for the reaction 3 C2H2(g) $\to$ C6H6 (I), is :
Solution
I. $\mathrm{C}_{6} \mathrm{H}_{6}(\ell)+\frac{15}{2} \mathrm{O}_{2}(\mathrm{~g}) \rightarrow 6 \mathrm{CO}_{2}(\mathrm{~g})+3 \mathrm{H}_{2} \mathrm{O}(\mathrm{g})$
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$\Delta \mathrm{H}_{1}=-3268 \mathrm{~kJ} / \mathrm{mol}$
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II. $\mathrm{C}_{2} \mathrm{H}_{2}(\mathrm{~g})+\frac{5}{2} \mathrm{O}_{2}(\mathrm{~g}) \rightarrow 2 \mathrm{CO}_{2}(\mathrm{~g})+\mathrm{H}_{2} \mathrm{O}(\mathrm{g})$
<br/><br/>
$\Delta \mathrm{H}_{2}=-1300 \mathrm{~kJ} / \mathrm{mol}$
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III. $3 \mathrm{C}_{2} \mathrm{H}_{2}(\mathrm{~g}) \rightarrow \mathrm{C}_{6} \mathrm{H}_{6}(\ell) \quad \Delta \mathrm{H}_{3}$
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Applying Hess's law of constant heat summation
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$$
\begin{aligned}
\Delta \mathrm{H}_{3} &=3 \times \Delta \mathrm{H}_{2}-\Delta \mathrm{H}_{1} \\\\
&=3 \times(-1300)-(-3268) \\\\
&=-632 \mathrm{~kJ} / \mathrm{mol}
\end{aligned}
$$
About this question
Subject: Chemistry · Chapter: Thermodynamics · Topic: Zeroth and First Law
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