Medium MCQ +4 / -1 PYQ · JEE Mains 2022

At 25$^\circ$C and 1 atm pressure, the enthalpy of combustion of benzene (I) and acetylene (g) are $-$ 3268 kJ mol$-$1 and $-$1300 kJ mol$-$1, respectively. The change in enthalpy for the reaction 3 C2H2(g) $\to$ C6H6 (I), is :

  1. A +324 kJ mol<sup>$-$1</sup>
  2. B +632 kJ mol<sup>$-$1</sup>
  3. C $-$ 632 kJ mol<sup>$-$1</sup> Correct answer
  4. D $-$ 732 kJ mol<sup>$-$1</sup>

Solution

I. $\mathrm{C}_{6} \mathrm{H}_{6}(\ell)+\frac{15}{2} \mathrm{O}_{2}(\mathrm{~g}) \rightarrow 6 \mathrm{CO}_{2}(\mathrm{~g})+3 \mathrm{H}_{2} \mathrm{O}(\mathrm{g})$ <br/><br/> $\Delta \mathrm{H}_{1}=-3268 \mathrm{~kJ} / \mathrm{mol}$ <br/><br/> II. $\mathrm{C}_{2} \mathrm{H}_{2}(\mathrm{~g})+\frac{5}{2} \mathrm{O}_{2}(\mathrm{~g}) \rightarrow 2 \mathrm{CO}_{2}(\mathrm{~g})+\mathrm{H}_{2} \mathrm{O}(\mathrm{g})$ <br/><br/> $\Delta \mathrm{H}_{2}=-1300 \mathrm{~kJ} / \mathrm{mol}$ <br/><br/> III. $3 \mathrm{C}_{2} \mathrm{H}_{2}(\mathrm{~g}) \rightarrow \mathrm{C}_{6} \mathrm{H}_{6}(\ell) \quad \Delta \mathrm{H}_{3}$ <br/><br/> Applying Hess's law of constant heat summation <br/><br/> $$ \begin{aligned} \Delta \mathrm{H}_{3} &=3 \times \Delta \mathrm{H}_{2}-\Delta \mathrm{H}_{1} \\\\ &=3 \times(-1300)-(-3268) \\\\ &=-632 \mathrm{~kJ} / \mathrm{mol} \end{aligned} $$

About this question

Subject: Chemistry · Chapter: Thermodynamics · Topic: Zeroth and First Law

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