Medium MCQ +4 / -1 PYQ · JEE Mains 2022

At 25$^\circ$C and 1 atm pressure, the enthalpies of combustion are as given below :

Substance ${H_2}$ C (graphite) ${C_2}{H_6}(g)$
${{{\Delta _c}{H^\Theta }} \over {kJ\,mo{l^{ - 1}}}}$ $- 286.0$ $- 394.0$ $- 1560.0$

The enthalpy of formation of ethane is

  1. A +54.0 kJ mol<sup>$-$1</sup>
  2. B $-$68.0 kJ mol<sup>$-$1</sup>
  3. C $-$86.0 kJ mol<sup>$-$1</sup> Correct answer
  4. D +97.0 kJ mol<sup>$-$1</sup>

Solution

$2 \mathrm{C}$ (graphite) $$+3 \mathrm{H}_{2}(\mathrm{~g}) \rightarrow \mathrm{C}_{2} \mathrm{H}_{6}(\mathrm{~g})$$<br/><br/> $\Delta \mathrm{H}_{\mathrm{r}}=+1560+2(-394)+3(-286)$<br/><br/> $=-86.0 \mathrm{~kJ} \mathrm{~mol}^{-1}$<br/><br/> Enthalpy of formation of C<sub>2</sub>H<sub>6</sub>(g) = –86.0 kJ mol–1

About this question

Subject: Chemistry · Chapter: Thermodynamics · Topic: Zeroth and First Law

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