Medium INTEGER +4 / -1 PYQ · JEE Mains 2020

The volume (in mL) of 0.125 M AgNO3 required to quantitatively precipitate chloride ions in 0.3 g of [Co(NH3)6]Cl3 is ________.
M[Co(NH3)6Cl3] = 267.46 g/mol
MAgNO3 = 169.87 g/mol

Answer (integer) 26

Solution

[Co(NH<sub>3</sub>)<sub>6</sub>]Cl<sub>3</sub> + 3AgNO<sub>3</sub> $\to$ 3AgCl <br><br><span style="display: inline-block;vertical-align: middle;"> <div style="text-align: center;border-bottom: 1px solid black;">Mole of [Co(NH<sub>3</sub>)<sub>6</sub>]Cl<sub>3</sub></div> <div style="text-align: center;">1</div> </span> = <span style="display: inline-block;vertical-align: middle;"> <div style="text-align: center;border-bottom: 1px solid black;">Mole of AgNO<sub>3</sub></div> <div style="text-align: center;">3</div> </span> <br><br>$\Rightarrow$ ${{0.3} \over {267.46}} = {{0.125 \times v \times {{10}^{ - 3}}} \over 3}$ <br><br>$\Rightarrow$ v = 26.92 ml

About this question

Subject: Chemistry · Chapter: Some Basic Concepts of Chemistry · Topic: Mole Concept

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