Identify the correct order of standard enthalpy of formation of sodium halides :
Solution
Lattice energy is directly proportional to the charges of the ions and inversely proportional to the sum of their radii:
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Lattice energy ∝ (Q₁Q₂) / (r₁ + r₂)
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As we move down the group, the size of the halide ions increases, resulting in a decrease in lattice energy. This leads to a decrease in the exothermicity of the lattice energy release during the formation of sodium halides.
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Thus, the correct order of standard enthalpy of formation of sodium halides, considering both lattice energy and electron affinity, is:
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$\mathrm{NaF}>\mathrm{NaCl}>\mathrm{NaBr}>\mathrm{NaI}$
About this question
Subject: Chemistry · Chapter: s-Block Elements · Topic: Alkali Metals
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