Given below are two statements:
Statement I : Group 13 trivalent halides get easily hydrolyzed by water due to their covalent nature.
Statement II : $\mathrm{AlCl}_3$ upon hydrolysis in acidified aqueous solution forms octahedral $\left[\mathrm{Al}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right]^{3+}$ ion.
In the light of the above statements, choose the correct answer from the options given below :
Solution
<p>In trivalent state most of the compounds being covalent are hydrolysed in water. Trichlorides on hydrolysis in water form tetrahedral $\left[\mathrm{M}(\mathrm{OH})_4\right]^{-}$ species, the hybridisation state of element $\mathrm{M}$ is $\mathrm{sp}^3$.</p>
<p>In case of aluminium, acidified aqueous solution forms octahedral $\left[\mathrm{Al}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right]^{3+}$ ion.</p>
About this question
Subject: Chemistry · Chapter: p-Block Elements · Topic: Group 13: Boron Family
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