Easy MCQ +4 / -1 PYQ · JEE Mains 2023

Which one of the following reactions does not occur during extraction of copper?

  1. A $\mathrm{2FeS + 3{O_2} \to 2FeO + 2S{O_2}}$
  2. B $\mathrm{FeO + Si{O_2} \to FeSi{O_3}}$
  3. C $\mathrm{CaO + Si{O_2} \to CaSi{O_3}}$ Correct answer
  4. D $\mathrm{2C{u_2}s + 3{O_2} \to 2C{u_2}O + 2S{O_2}}$

Solution

$$ \begin{aligned} & \mathrm{CuFeS}_2+\mathrm{O}_2 \stackrel{\text { Partial roasting }}{\longrightarrow} \\\\ & \mathrm{Cu}_2 \mathrm{~S}+\mathrm{FeO}+\mathrm{SO}_2+\underset{\text { very small }}{\mathrm{FeS}}+\underset{\text { very small }}{\mathrm{Cu}_2 \mathrm{O}} \\\\ & \mathrm{Cu}_2 \mathrm{~S}+\mathrm{O}_2 \rightarrow \mathrm{Cu}_2 \mathrm{O}+\mathrm{SO}_2 \\\\ & \mathrm{FeS}+\mathrm{O}_2 \rightarrow \mathrm{FeO}+\mathrm{SO}_2 \\\\ & \mathrm{FeO}+\mathrm{SiO}_2 \rightarrow \mathrm{FeSiO}_3 \end{aligned} $$<br/><br/> No formation of calcium silicate $\left(\mathrm{CaSiO}_3\right)$ in extraction of $\mathrm{Cu}$.

About this question

Subject: Chemistry · Chapter: p-Block Elements · Topic: Group 13: Boron Family

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