Medium MCQ +4 / -1 PYQ · JEE Mains 2025

The maximum covalency of a non-metallic group 15 element ' E ' with weakest $\mathrm{E}-\mathrm{E}$ bond is :

  1. A 5
  2. B 3
  3. C 4 Correct answer
  4. D 6

Solution

<p>Among the group 15 elements (N, P, As, Sb, Bi), the lightest two (N and P) are commonly considered nonmetals. Of these, <strong>nitrogen</strong> (N) is known to have the <strong>weakest single bond</strong> to itself (N–N). </p> <p>The <strong>N–N</strong> single‐bond enthalpy ($\approx 160$\,kJ/mol) is lower (weaker) than the <strong>P–P</strong> single‐bond enthalpy ($\approx 200$\,kJ/mol). </p> <p>Therefore, the “nonmetallic group 15 element with the weakest E–E bond” is <strong>nitrogen</strong>.</p> <hr /> <h3>Maximum Covalency of Nitrogen</h3> <p>Although nitrogen typically forms <strong>three</strong> covalent bonds in neutral compounds (e.g., $\mathrm{NH_3}$), it can expand to <strong>four</strong> bonds in certain cationic species such as ammonium $\mathrm{NH_4}^+$ or $\mathrm{NF_4}^+$. In such species, nitrogen has a formal positive charge but is still forming four covalent bonds.</p> <p>Hence, the <strong>maximum covalency</strong> of nitrogen is <strong>4</strong>.</p> <hr /> <p><strong>Answer: 4 (Option C).</strong></p>

About this question

Subject: Chemistry · Chapter: p-Block Elements · Topic: Group 13: Boron Family

This question is part of PrepWiser's free JEE Main question bank. 300 more solved questions on p-Block Elements are available — start with the harder ones if your accuracy is >70%.

Drill 25 more like these. Every day. Free.

PrepWiser turns these solved questions into a daily practice loop. Chapter-wise drills, full mocks, AI doubt chat. No auto-renew.

Start free →