Easy MCQ +4 / -1 PYQ · JEE Mains 2021

In basic medium, H2O2 exhibits which of the following reactions?

(A) Mn2+ $\to$ Mn4+

(B) I2 $\to$ I$-$

(C) PbS $\to$ PbSO4

Choose the most appropriate answer from the options given below :

  1. A (B) only
  2. B (A), (B) only Correct answer
  3. C (A) only
  4. D (A), (C) only

Solution

In basic medium, oxidising action of H<sub>2</sub>O<sub>2</sub>.<br><br> Mn<sup>2+</sup> + H<sub>2</sub>O<sub>2</sub> $\to$ Mn<sup>+4</sup> + 2OH<sup>–</sup><br><br> In basic medium, reducing action of H<sub>2</sub>O<sub>2</sub>.<br><br> I<sub>2</sub> + H<sub>2</sub>O<sub>2</sub> + 2OH<sup>–</sup> $\to$ 2I<sup>–</sup> + 2H<sub>2</sub>O + O<sub>2</sub><br><br> In acidic medium, oxidising action of H<sub>2</sub>O<sub>2</sub>.<br><br> PbS(s) + 4H<sub>2</sub>O<sub>2</sub>(aq) $\to$ PbSO<sub>4</sub>(s) + 4H<sub>2</sub>O(l)

About this question

Subject: Chemistry · Chapter: p-Block Elements · Topic: Group 13: Boron Family

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