Medium MCQ +4 / -1 PYQ · JEE Mains 2024

Evaluate the following statements related to group 14 elements for their correctness.

(A) Covalent radius decreases down the group from $\mathrm{C}$ to $\mathrm{Pb}$ in a regular manner.

(B) Electronegativity decreases from $\mathrm{C}$ to $\mathrm{Pb}$ down the group gradually.

(C) Maximum covalance of $\mathrm{C}$ is 4 whereas other elements can expand their covalance due to presence of d orbitals.

(D) Heavier elements do not form $\mathrm{p} \pi-\mathrm{p} \pi$ bonds.

(E) Carbon can exhibit negative oxidation states.

Choose the correct answer from the options given below :

  1. A (A), (B) and (C) Only
  2. B (A) and (B) Only
  3. C (C), (D) and (E) Only Correct answer
  4. D (C) and (D) Only

Solution

<p>(A) Covalent radius of group 14 elements increases from $\mathrm{C}$ to $\mathrm{Pb}$.</p> <p>(B) Electronegativity decreases from $\mathrm{C}$ to $\mathrm{Si}$ and thereafter it remains more or less constant.</p> <p>(C) Maximum covalency of $\mathrm{C}$ is 4 as the outermost shell of $\mathrm{C}$ is $2^{\text {nd }}$ shell and it cannot expand its octet. But other elements can expand their covalency due to the availability of vacant d-orbitals.</p> <p>(D) Heavier elements do not form $\mathrm{p} \pi-\mathrm{p} \pi$ bonds due to their larger atomic size.</p> <p>(E) Carbon can show negative oxidation states when it is covalently bonded to less electronegative elements like $\mathrm{CH}_4$.</p>

About this question

Subject: Chemistry · Chapter: p-Block Elements · Topic: Group 13: Boron Family

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