Medium MCQ +4 / -1 PYQ · JEE Mains 2022

Which one of the following reactions indicates the reducing ability of hydrogen peroxide in basic medium?

  1. A HOCl + H<sub>2</sub>O<sub>2</sub> $\to$ H<sub>3</sub>O<sup>+</sup> + Cl<sup>$-$</sup> + O<sub>2</sub>
  2. B PbS + 4H<sub>2</sub>O<sub>2</sub> $\to$ PbSO<sub>4</sub> + 4H<sub>2</sub>O
  3. C 2MnO$_4^ -$ + 3H<sub>2</sub>O<sub>2</sub> $\to$ 2MnO<sub>2</sub> + 3O<sub>2</sub> + 2H<sub>2</sub>O + 2OH<sup>$-$</sup> Correct answer
  4. D Mn<sup>2+</sup> + H<sub>2</sub>O<sub>2</sub> $\to$ Mn<sup>4+</sup> + 2OH<sup>$-$</sup>

Solution

$2 \mathrm{Mn}\overset{+7}{\mathrm{O}_{4}^{-}}+3 \mathrm{H}_{2} \mathrm{O}_{2} \rightarrow$ <br/><br/> $2 \mathrm{Mn}\overset{+4}{\mathrm{O}_{2}}+3 \mathrm{O}_{2}+2 \mathrm{H}_{2} \mathrm{O}+2 \mathrm{O} \overline{\mathrm{H}}$ <br/><br/> In basic medium $\mathrm{MnO}_{4}^{-}$is reduced to $\mathrm{MnO}_{2}$, whereas in acidic medium it is reduced to $\mathrm{Mn}^{+2}$.

About this question

Subject: Chemistry · Chapter: p-Block Elements · Topic: Group 13: Boron Family

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