Medium MCQ +4 / -1 PYQ · JEE Mains 2022

Given are two statements one is labelled as Assertion A and other is labelled as Reason R.

Assertion A : Magnesium can reduce Al2O3 at a temperature below 1350$^\circ$C, while above 1350$^\circ$C, while above 1350$^\circ$C aluminium can reduce MgO.

Reason R : The melting and boiling points of magnesium are lower than those of aluminium.

n light of the above statements, choose most appropriate answer from the options given below :

  1. A Both A and R are correct, and R is correct explanation of A.
  2. B Both A and R are correct, but R is NOT the correct explanation of A. Correct answer
  3. C A is correct R is not correct.
  4. D A is not correct, R is correct.

Solution

Magnesium can reduce Al<sub>2</sub>O<sub>3</sub> at a temperature below 1350°C while above 1350°C aluminium can reduce MgO because below 1350°C $\Delta$G of MgO (formation) is more negative and above 1350°C $\Delta$G of Al<sub>2</sub>O<sub>3</sub> (formation) is more negative.<br/><br/> The melting and boiling point of magnesium are lower than those of aluminium but it is not the correct reason.

About this question

Subject: Chemistry · Chapter: p-Block Elements · Topic: Group 13: Boron Family

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