Medium MCQ +4 / -1 PYQ · JEE Mains 2022

Given below are two statements :

Statement I : According to Ellingham diagram, any metal oxide with higher $\Delta$G$^\circ$ is more stable than the one with lower $\Delta$G$^\circ$.

Statement II : The metal involved in the formation of oxide placed lower in the Ellingham diagram can reduce the oxide of a metal placed higher in the diagram.

In the light of the above statements, choose the most appropriate answer from the options given below :

  1. A Both Statement I and Statement II are correct.
  2. B Both Statement I and Statement II are incorrect.
  3. C Statement I is correct but Statement II is incorrect.
  4. D Statement I is incorrect but Statement II is correct. Correct answer

Solution

Ellingham diagram is plot of $\Delta$G vs T. The criterion for the feasibility of a thermal reduction is that at a given temperature Gibbs energy change of a reaction must be negative. The change in Gibbs energy, $\Delta$G for any process at any specified temperature is given by the equation<br/><br/> $\Delta$G = $\Delta$H - T$\Delta$S<br/><br/> where $\Delta$H = enthalpy change and $\Delta$S = entropy change<br/><br/> According to the ellingham diagram, any metal oxide with higher $\Delta$G° has a tendency of getting reduced by the metal whose metal oxide has lower value of $\Delta$G°.

About this question

Subject: Chemistry · Chapter: p-Block Elements · Topic: Group 13: Boron Family

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