Medium MCQ +4 / -1 PYQ · JEE Mains 2024

Choose the correct statements about the hydrides of group 15 elements.

A. The stability of the hydrides decreases in the order $\mathrm{NH}_3>\mathrm{PH}_3>\mathrm{AsH}_3> \mathrm{SbH}_3>\mathrm{BiH}_3$.

B. The reducing ability of the hydride increases in the order $\mathrm{NH}_3<\mathrm{PH}_3<\mathrm{AsH}_3 <\mathrm{SbH}_3<\mathrm{BiH}_3$.

C. Among the hydrides, $\mathrm{NH}_3$ is strong reducing agent while $\mathrm{BiH}_3$ is mild reducing agent.

D. The basicity of the hydrides increases in the order $\mathrm{NH}_3<\mathrm{PH}_3<\mathrm{AsH}_3< \mathrm{SbH}_3<\mathrm{BiH}_3$.

Choose the most appropriate from the options given below :

  1. A C and D only
  2. B A and D only
  3. C A and B only Correct answer
  4. D B and C only

Solution

<p>On moving down the group, bond strength of $\mathrm{M}-\mathrm{H}$ bond decreases, which reduces the thermal stability but increases reducing nature of hydrides, hence A and B are correct statements.</p>

About this question

Subject: Chemistry · Chapter: p-Block Elements · Topic: Group 13: Boron Family

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