Medium MCQ +4 / -1 PYQ · JEE Mains 2024

Given below are two statements : one is labelled as Assertion (A) and the other is labelled as Reason (R).

Assertion (A) : Both rhombic and monoclinic sulphur exist as $\mathrm{S}_8$ while oxygen exists as $\mathrm{O}_2$.

Reason (R) : Oxygen forms $p \pi-p \pi$ multiple bonds with itself and other elements having small size and high electronegativity like $\mathrm{C}, \mathrm{N}$, which is not possible for sulphur.

In the light of the above statements, choose the most appropriate answer from the options given below :

  1. A Both (A) and (R) are correct but (R) is not the correct explanation of (A)
  2. B (A) is correct but (R) is not correct
  3. C (A) is not correct but (R) is correct
  4. D Both $(\mathbf{A})$ and $(\mathbf{R})$ are correct and $(\mathbf{R})$ is the correct explanation of $(\mathbf{A})$ Correct answer

Solution

<p>Oxygen exists as $\mathrm{O}_2$</p> <p>Sulphur exists as $\mathrm{S}_8$</p> <p>Because of small size of oxygen, oxygen can form $2 \mathrm{p}_\pi-2 \mathrm{p}_\pi$ bond.</p> <p>$\Rightarrow$ Assertion (A) is correct.</p> <p>$\Rightarrow$ Reason (R) is correct.</p> <p>Reason (R) is correct explanation of Assertion (A).</p>

About this question

Subject: Chemistry · Chapter: p-Block Elements · Topic: Group 13: Boron Family

This question is part of PrepWiser's free JEE Main question bank. 300 more solved questions on p-Block Elements are available — start with the harder ones if your accuracy is >70%.

Drill 25 more like these. Every day. Free.

PrepWiser turns these solved questions into a daily practice loop. Chapter-wise drills, full mocks, AI doubt chat. No auto-renew.

Start free →