Easy MCQ +4 / -1 PYQ · JEE Mains 2025

Arrange the following in increasing order of solubility product :

$\mathrm{Ca}(\mathrm{OH})_2, \mathrm{AgBr}, \mathrm{PbS}, \mathrm{HgS}$

  1. A $\mathrm{PbS}<\mathrm{HgS}<\mathrm{Ca}(\mathrm{OH})_2<\mathrm{AgBr}$
  2. B $\mathrm{HgS}<\mathrm{AgBr}<\mathrm{PbS}<\mathrm{Ca}(\mathrm{OH})_2$
  3. C $\mathrm{HgS}<\mathrm{PbS}<\mathrm{AgBr}<\mathrm{Ca}(\mathrm{OH})_2$ Correct answer
  4. D $\mathrm{Ca}(\mathrm{OH})_2<\mathrm{AgBr}<\mathrm{HgS}<\mathrm{PbS}$

Solution

<p>Based on the Ksp values and salt analysis cation identification, we can say that order of Ksp value is:</p> <p>$\mathrm{HgS}<\mathrm{PbS}<\mathrm{AgBr}<\mathrm{Ca}(\mathrm{OH})_2$</p> <p>Ksp values</p> <p>$$\begin{aligned} & \mathrm{HgS} \rightarrow 4 \times 10^{-53} \\ & \mathrm{PbS} \rightarrow 8 \times 10^{-28} \\ & \mathrm{AgBr} \rightarrow 5 \times 10^{-13} \\ & \mathrm{Ca}(\mathrm{OH})_2 \rightarrow 5.5 \times 10^{-6} \end{aligned}$$</p>

About this question

Subject: Chemistry · Chapter: Equilibrium · Topic: Chemical Equilibrium and Kc, Kp

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