Easy MCQ +4 / -1 PYQ · JEE Mains 2023

$25 \mathrm{~mL}$ of silver nitrate solution (1M) is added dropwise to $25 \mathrm{~mL}$ of potassium iodide $(1.05 \mathrm{M})$ solution. The ion(s) present in very small quantity in the solution is/are :

  1. A $\mathrm{I^-}$ only
  2. B $\mathrm{K^+}$ only
  3. C $\mathrm{Ag^+}$ and $\mathrm{I^-}$ both Correct answer
  4. D $\mathrm{NO_3^-}$ only

Solution

The reaction between silver nitrate (AgNO<sub>3</sub>) and potassium iodide (KI) forms silver iodide (AgI), which is practically insoluble in water. The reaction is as follows : <br/><br/>AgNO<sub>3</sub>(aq) + KI(aq) → AgI(s) + KNO<sub>3</sub>(aq) <br/><br/>Although the reaction stoichiometry indicates that iodide ions (I<sup>-</sup>) and silver ions (Ag<sup>+</sup>) are produced, silver iodide (AgI) precipitates out of the solution due to its low solubility, and very little Ag<sup>+</sup> and I<sup>-</sup> ions remain in the solution. Hence, their concentration in the solution will be negligible. <br/><br/>So, the correct answer should be : <br/><br/>Option C : Ag+ and I- both

About this question

Subject: Chemistry · Chapter: Equilibrium · Topic: Chemical Equilibrium and Kc, Kp

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