Medium MCQ +4 / -1 PYQ · JEE Mains 2024

Which of the following electronic configuration would be associated with the highest magnetic moment?

  1. A $[\mathrm{Ar}] 3 \mathrm{~d}^7$
  2. B $[\mathrm{Ar}] 3 \mathrm{~d}^8$
  3. C $[\mathrm{Ar}] 3 \mathrm{~d}^3$
  4. D $[\mathrm{Ar}] 3 \mathrm{~d}^6$ Correct answer

Solution

<p>The magnetic moment of an atom or ion with unpaired electrons is given by the formula $\mu = \sqrt{n(n+2)}$ Bohr magnetons (BM), where $n$ is the number of unpaired electrons. The magnetic moment depends on the number of unpaired electrons: more unpaired electrons lead to a higher magnetic moment.</p> <p>Looking at the given options with respect to their electron configurations and calculating their respective magnetic moments based on their unpaired electrons: </p><ul><li>$[\mathrm{Ar}] 3 \mathrm{~d}^7$ has 3 unpaired electrons, yielding a magnetic moment of $\sqrt{15}$ BM.</li><li>$[\mathrm{Ar}] 3 \mathrm{~d}^8$ has 2 unpaired electrons, for a magnetic moment of $\sqrt{8}$ BM.</li><li>$[\mathrm{Ar}] 3 \mathrm{~d}^3$ also has 3 unpaired electrons, similar to $3 \mathrm{~d}^7$, so its magnetic moment is likewise $\sqrt{15}$ BM.</li><li>Finally, $[\mathrm{Ar}] 3 \mathrm{~d}^6$ has 4 unpaired electrons, resulting in the highest magnetic moment among the options, $\sqrt{24}$ BM.</li></ul> <p>Hence, the electron configuration associated with the highest magnetic moment is $[\mathrm{Ar}] 3 \mathrm{~d}^6$.</p>

About this question

Subject: Chemistry · Chapter: d and f Block Elements · Topic: Properties of Transition Metals

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