Easy MCQ +4 / -1 PYQ · JEE Mains 2022

The reaction of zinc with excess of aqueous alkali, evolves hydrogen gas and gives :

  1. A $\mathrm{Zn}(\mathrm{OH})_{2}$
  2. B $\mathrm{ZnO}$
  3. C $\left[\mathrm{Zn}(\mathrm{OH})_{4}\right]^{2-}$ Correct answer
  4. D $\left[\mathrm{ZnO}_{2}\right]^{2-}$

Solution

Zinc dissolves in excess of aqueous alkali. <br/><br/> $$\mathrm{Zn}+2 \mathrm{OH}^{-}+2 \mathrm{H}_{2} \mathrm{O} \longrightarrow\left[\mathrm{Zn}(\mathrm{OH})_{4}\right]^{2-}+\mathrm{H}_{2} \uparrow$$ (Tetrahydroxozincate(II) ion) <br/><br/> However, this reaction in NCERT is given as <br/><br/> $$\mathrm{Zn}+2 \mathrm{NaOH} \longrightarrow \mathrm{Na}_{2} \mathrm{ZnO}_{2}+\mathrm{H}_{2} \uparrow$$ <br/><br/> $\mathrm{ZnO}_{2}^{2-}$ is anhydrous form of $\left[\mathrm{Zn}(\mathrm{OH})_{4}\right]^{2-}$. <br/><br/> $$\mathrm{ZnO}_{2}^{2-}+2 \mathrm{H}_{2} \mathrm{O} \rightleftharpoons\left[\mathrm{Zn}(\mathrm{OH})_{4}\right]^{2-}$$ <br/><br/> So in aqueous medium best answer of this question is $\left[\mathrm{Zn}(\mathrm{OH})_{4}\right]^{2-}$.

About this question

Subject: Chemistry · Chapter: d and f Block Elements · Topic: Properties of Transition Metals

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