The reaction of zinc with excess of aqueous alkali, evolves hydrogen gas and gives :
Solution
Zinc dissolves in excess of aqueous alkali.
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$$\mathrm{Zn}+2 \mathrm{OH}^{-}+2 \mathrm{H}_{2} \mathrm{O} \longrightarrow\left[\mathrm{Zn}(\mathrm{OH})_{4}\right]^{2-}+\mathrm{H}_{2} \uparrow$$ (Tetrahydroxozincate(II) ion)
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However, this reaction in NCERT is given as
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$$\mathrm{Zn}+2 \mathrm{NaOH} \longrightarrow \mathrm{Na}_{2} \mathrm{ZnO}_{2}+\mathrm{H}_{2} \uparrow$$
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$\mathrm{ZnO}_{2}^{2-}$ is anhydrous form of $\left[\mathrm{Zn}(\mathrm{OH})_{4}\right]^{2-}$.
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$$\mathrm{ZnO}_{2}^{2-}+2 \mathrm{H}_{2} \mathrm{O} \rightleftharpoons\left[\mathrm{Zn}(\mathrm{OH})_{4}\right]^{2-}$$
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So in aqueous medium best answer of this question is $\left[\mathrm{Zn}(\mathrm{OH})_{4}\right]^{2-}$.
About this question
Subject: Chemistry · Chapter: d and f Block Elements · Topic: Properties of Transition Metals
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