Medium MCQ +4 / -1 PYQ · JEE Mains 2023

Given below are two statements : one is labelled as Assertion (A) and the other is labelled as Reason (R).

Assertion (A) : $\mathrm{Cu^{2+}}$ in water is more stable than $\mathrm{Cu^{+}}$.

Reason (R) : Enthalpy of hydration for $\mathrm{Cu^{2+}}$ is much less than that of $\mathrm{Cu^{+}}$.

In the light of the above statements, choose the correct answer from the options given below :

  1. A (A) is correct but (R) is not correct Correct answer
  2. B Both (A) and (R) are correct but (R) is not the correct explanation of (A)
  3. C (A) is not correct but (R) is correct
  4. D Both (A) and (R) are correct and (R) is the correct explanation of (A)

Solution

Cu<sup>2+</sup> ion is more stable than Cu<sup>+</sup> ion due to high charge density on Cu<sup>2+</sup> ion, it has higher hydration energy when it bonds to water molecules thus it forms stronger bonds. <br/><br/>$\therefore$ (A) is correct but (R) is not correct.

About this question

Subject: Chemistry · Chapter: d and f Block Elements · Topic: Properties of Transition Metals

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