Medium INTEGER +4 / -1 PYQ · JEE Mains 2023

The number of species from the following which have square pyramidal structure is _________

$$\mathrm{PF}_{5}, \mathrm{BrF}_{4}^{-}, \mathrm{IF}_{5}, \mathrm{BrF}_{5}, \mathrm{XeOF}_{4}, \mathrm{ICl}_{4}^{-}$$

Answer (integer) 3

Solution

<p>A square pyramidal structure has five bonds and one lone pair, making a total of six electron pairs around the central atom. The geometry of such a molecule can be analyzed using the VSEPR theory.</p> <ol> <li>$\mathrm{PF}_{5}$: 5 bond pairs and 0 lone pairs, so its geometry is trigonal bipyramidal, not square pyramidal.</li> <br/><li>$\mathrm{BrF}_{4}^{-}$: 4 bond pairs and 2 lone pairs, so its geometry is square planar, not square pyramidal.</li><br/> <li>$\mathrm{IF}_{5}$: 5 bond pairs and 1 lone pair, so its geometry is square pyramidal.</li><br/> <li>$\mathrm{BrF}_{5}$: 5 bond pairs and 1 lone pair, so its geometry is square pyramidal.</li> <br/><li>$\mathrm{XeOF}_{4}$: 5 bond pairs and 1 lone pair, so its geometry is square pyramidal.</li><br/> <li>$\mathrm{ICl}_{4}^{-}$: 4 bond pairs and 2 lone pairs, so its geometry is square planar, not square pyramidal.</li> </ol> <p>So the number of species from the given list that have a square pyramidal structure is 3.</p>

About this question

Subject: Chemistry · Chapter: Chemical Bonding and Molecular Structure · Topic: Ionic and Covalent Bonding

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