Medium MCQ +4 / -1 PYQ · JEE Mains 2023

In which of the following processes, the bond order increases and paramagnetic character changes to diamagnetic one ?

  1. A $\mathrm{O}_{2} \rightarrow \mathrm{O}_{2}^{2-}$
  2. B $\mathrm{N}_{2} \rightarrow \mathrm{N}_{2}^{+}$
  3. C $\mathrm{NO} \rightarrow \mathrm{NO}^{+}$ Correct answer
  4. D $\mathrm{O}_{2} \rightarrow \mathrm{O}_{2}^{+}$

Solution

Let's analyze each option: <br/><br/> Option A: $\mathrm{O}_{2} \rightarrow \mathrm{O}_{2}^{2-}$<br/><br/> The bond order of $\mathrm{O}_{2}$ is 2 and it is paramagnetic. When two electrons are added to form $\mathrm{O}_{2}^{2-}$, the bond order becomes 1 (decreases) and it becomes diamagnetic. This option does not meet the required conditions. <br/><br/> Option B: $\mathrm{N}_{2} \rightarrow \mathrm{N}_{2}^{+}$<br/><br/> The bond order of $\mathrm{N}_{2}$ is 3 and it is diamagnetic. When one electron is removed to form $\mathrm{N}_{2}^{+}$, the bond order becomes 2.5 (decreases) and it remains diamagnetic. This option does not meet the required conditions. <br/><br/> Option C: $\mathrm{NO} \rightarrow \mathrm{NO}^{+}$<br/><br/> The bond order of $\mathrm{NO}$ is 2.5 and it is paramagnetic. When one electron is removed to form $\mathrm{NO}^{+}$, the bond order becomes 3 (increases) and it becomes diamagnetic. This option meets the required conditions. <br/><br/> Option D: $\mathrm{O}_{2} \rightarrow \mathrm{O}_{2}^{+}$<br/><br/> The bond order of $\mathrm{O}_{2}$ is 2 and it is paramagnetic. When one electron is removed to form $\mathrm{O}_{2}^{+}$, the bond order becomes 2.5 (increases) and it remains paramagnetic. This option does not meet the required conditions. <br/><br/> Therefore, the correct answer is $\mathrm{NO} \rightarrow \mathrm{NO}^{+}$.

About this question

Subject: Chemistry · Chapter: Chemical Bonding and Molecular Structure · Topic: Ionic and Covalent Bonding

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