Medium INTEGER +4 / -1 PYQ · JEE Mains 2024

Total number of electrons present in $\left(\pi^*\right)$ molecular orbitals of $\mathrm{O}_2, \mathrm{O}_2^{+}$ and $\mathrm{O}_2^{-}$ is ________.

Answer (integer) 6

Solution

<p>$$\begin{aligned} & \mathrm{O}_2(16 \mathrm{e}):\left(\sigma_{1 \mathrm{~s}}\right)^2\left(\sigma_{1 \mathrm{~s}}^*\right)^2\left(\sigma_{2 \mathrm{~s}}\right)^2\left(\sigma_{2 \mathrm{~s}}^*\right)^2 \\ & \left(\sigma_{2 \mathrm{p}}\right)^2\left[\left(\pi_{2 \mathrm{p}}\right)^2=\left(\pi_{2 \mathrm{p}}\right)^2\right],\left[\left(\pi_{2 \mathrm{p}}^*\right)^1=\left(\pi_{2 \mathrm{p}}^*\right)^1\right] \end{aligned}$$</p> <p>Number of $\mathrm{e}^{-}$ present in $\left(\pi^*\right)$ of $\mathrm{O}_2=2$</p> <p>Number of $\mathrm{e}^{-}$ present in $\left(\pi^*\right)$ of $\mathrm{O}_2^{+}=1$</p> Number of $\mathrm{e}^{-}$ present in $\left(\pi^*\right)$ of $\mathrm{O}_2^{-}=3$</p> <p>So total $\mathrm{e}^{-}$ in $\left(\pi^*\right)=2+1+3=6$</p>

About this question

Subject: Chemistry · Chapter: Chemical Bonding and Molecular Structure · Topic: Ionic and Covalent Bonding

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