Medium MCQ +4 / -1 PYQ · JEE Mains 2024

Match List I with List II.

LIST I
LIST II
A. $
\mathrm{ICl}
$
I. T - shape
B. $
\mathrm{ICl}_3
$
II. Square pyramidal
C. $
\mathrm{ClF}_5
$
III. Pentagonal bipyramidal
D. $
\mathrm{IF}_7
$
IV. Linear

Choose the correct answer from the options given below :

  1. A (A)-(I), (B)-(IV), (C)-(III), (D)-(II)
  2. B (A)-(IV), (B)-(I), (C)-(II), (D)-(III) Correct answer
  3. C (A)-(I), (B)-(III), (C)-(II), (D)-(IV)
  4. D (A)-(IV), (B)-(III), (C)-(II), (D)-(I)

Solution

<p>$$\begin{aligned} & \mathrm{ICl} \rightarrow s p^3 \rightarrow 1 \mathrm{bp}+3 \mathrm{lp} \rightarrow \text { Linear } \\ & \mathrm{ICl}_3 \rightarrow s p^3 d \rightarrow 3 \mathrm{bp}+2 \mathrm{lp} \rightarrow \mathrm{T} \text {-shape } \\ & \mathrm{CIF}_5 \rightarrow s p^3 d^2 \rightarrow 5 \mathrm{bp}+1 \mathrm{lp} \rightarrow \text { Square Pyramidal } \\ & \mathrm{IF}_7 \rightarrow s p^3 d^3 \rightarrow 7 \text { bp only } \rightarrow \text { Pentagonal bipyramidal } \\ & \text { (A)-(IV), (B)-(I), (C)-(II), D-(III) } \end{aligned}$$</p>

About this question

Subject: Chemistry · Chapter: Chemical Bonding and Molecular Structure · Topic: Ionic and Covalent Bonding

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