Which of the following sets of quantum numbers is not allowed?

1. A $\mathrm{n}=3,1=2, \mathrm{~m}_{\mathrm{l}}=0, \mathrm{~s}=+\frac{1}{2}$
2. B $$ \mathrm{n}=3, \mathrm{l}=2, \mathrm{~m}_{\mathrm{l}}=-2, \mathrm{~s}=+\frac{1}{2} $$
3. C $$ \mathrm{n}=3, \mathrm{l}=3, \mathrm{~m}_{\mathrm{l}}=-3, \mathrm{~s}=-\frac{1}{2} $$ Correct answer
4. D $\mathrm{n}=3, \mathrm{l}=0, \mathrm{~m}_{1}=0, \mathrm{~s}=-\frac{1}{2}$