Medium MCQ +4 / -1 PYQ · JEE Mains 2020

The shortest wavelength of H atom in the Lyman series is $\lambda$1. The longest wavelength in the Balmar series of He+ is :

  1. A ${{5{\lambda _1}} \over 9}$
  2. B ${{36{\lambda _1}} \over 5}$
  3. C ${{27{\lambda _1}} \over 5}$
  4. D ${{9{\lambda _1}} \over 5}$ Correct answer

Solution

For Shortest wavelength energy should be maximum. <br><br>For maximum energy transition must be form n = $\infty$ to n = 1. <br><br>$${1 \over {{\lambda _1}}} = {R_H}{\left( 1 \right)^2}\left[ {{1 \over 1} - 0} \right]$$ <br><br>$\Rightarrow$ ${1 \over {{\lambda _1}}} = {R_H}$ <br><br>For longest wavelength, $\Delta$E = minimum. <br>For Blamer series n = 3 to n = 2 will have $\Delta$E minimum for He<sup>+</sup>, Z = 2 <br><br>So $${1 \over {{\lambda _2}}} = {R_H}{\left( 2 \right)^2}\left[ {{1 \over 4} - {1 \over 9}} \right]$$ <br><br>$\Rightarrow$ ${1 \over {{\lambda _2}}} = {R_H} \times {5 \over 9}$ <br><br>$\Rightarrow$ ${\lambda _2} = {\lambda _1} \times {9 \over 5}$

About this question

Subject: Chemistry · Chapter: Atomic Structure · Topic: Bohr's Model

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