The shortest wavelength of H atom in the Lyman series is $\lambda$1. The longest wavelength in the Balmar series of He+ is :
Solution
For Shortest wavelength energy should be maximum.
<br><br>For maximum energy transition must be form n = $\infty$ to n = 1.
<br><br>$${1 \over {{\lambda _1}}} = {R_H}{\left( 1 \right)^2}\left[ {{1 \over 1} - 0} \right]$$
<br><br>$\Rightarrow$ ${1 \over {{\lambda _1}}} = {R_H}$
<br><br>For longest wavelength, $\Delta$E = minimum. <br>For Blamer series n = 3 to n = 2 will have $\Delta$E minimum
for He<sup>+</sup>,
Z = 2
<br><br>So $${1 \over {{\lambda _2}}} = {R_H}{\left( 2 \right)^2}\left[ {{1 \over 4} - {1 \over 9}} \right]$$
<br><br>$\Rightarrow$ ${1 \over {{\lambda _2}}} = {R_H} \times {5 \over 9}$
<br><br>$\Rightarrow$ ${\lambda _2} = {\lambda _1} \times {9 \over 5}$
About this question
Subject: Chemistry · Chapter: Atomic Structure · Topic: Bohr's Model
This question is part of PrepWiser's free JEE Main question bank. 122 more solved questions on Atomic Structure are available — start with the harder ones if your accuracy is >70%.