Medium MCQ +4 / -1 PYQ · JEE Mains 2023

The shortest wavelength of hydrogen atom in Lyman series is $\lambda$. The longest wavelength is Balmer series of He$^+$ is

  1. A $\frac{36\lambda}{5}$
  2. B $\frac{5}{9\lambda}$
  3. C $\frac{9\lambda}{5}$ Correct answer
  4. D $\frac{5\lambda}{9}$

Solution

For H: $\frac{1}{\lambda}=\mathrm{R}_{\mathrm{H}} \times 1^{2}\left(\frac{1}{1^{2}}-\frac{1}{\infty^{2}}\right) \quad...(1)$ <br/><br/> $$ \frac{1}{\lambda_{\mathrm{He}^{+}}}=\mathrm{R}_{\mathrm{H}} \times 2^{2} \times\left(\frac{1}{4}-\frac{1}{9}\right)\quad...(2) $$ <br/><br/> From (1) &amp; (2) $\frac{\lambda_{\mathrm{He}^{+}}}{\lambda}=\frac{9}{5}$ <br/><br/> $$ \begin{aligned} & \lambda_{\mathrm{He}^{+}}=\lambda \times \frac{9}{5} \\ & \lambda_{\mathrm{He}^{+}}=\frac{9 \lambda}{5} \end{aligned} $$

About this question

Subject: Chemistry · Chapter: Atomic Structure · Topic: Bohr's Model

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