Medium MCQ +4 / -1 PYQ · JEE Mains 2022

Which of the following statements are correct?

(A) The electronic configuration of Cr is [Ar] 3d5 4s1.

(B) The magnetic quantum number may have a negative value.

(C) In the ground state of an atom, the orbitals are filled in order of their increasing energies.

(D) The total number of nodes are given by n $-$ 2.

Choose the most appropriate answer from the options given below :

  1. A (A), (C) and (D) only
  2. B (A) and (B) only
  3. C (A) and (C) only
  4. D (A), (B) and (C) only Correct answer

Solution

<p>(A) Cr (24) = 1s<sup>2</sup> 2s<sup>2</sup> 2p<sup>6</sup> 3s<sup>2</sup> 3p<sup>6</sup> 3d<sup>5</sup> 4s<sup>1</sup></p> <p>= [Ar] 3d<sup>5</sup> 4s<sup>1</sup></p> <p>(B) Magnetic quantum number (m) values ranging from $-$ l to + l including zero.</p> <p>$\therefore$ It can have negative value.</p> <p>(C) According to Aufbau rule, electrons are filled first in these orbitals which have low energy.</p> <p>$\therefore$ Statement C is correct.</p> <p>(D) We know,</p> <p>Number of Radial nodes = n $-$ l $-$ 1</p> <p>and number of Angular nodes = l</p> <p>$\therefore$ Total nodes = n $-$ l $-$ 1 + 1 = n $-$ 1</p>

About this question

Subject: Chemistry · Chapter: Atomic Structure · Topic: Bohr's Model

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